Controlling On-Surface Photoactivity: The Impact of π-Conjugation in Anhydride-Functionalized Molecules on a Semiconductor Surface
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
no. 21-17194L
Grantová Agentura České Republiky
CZ.02.01.01/00/22_010/0002906
Grantová Agentura České Republiky
no. 20-13692X
Grantová Agentura České Republiky
CZ.10.03.01/00/22_003/0000048
European Union: REFRESH-Research Excellence For Region Sustainability and High-tech Industries
LM2023051
CzechNanoLab Research Infrastructure supported by MEYS CR
Grant# 202775
Swiss National Science Foundation - Switzerland
PubMed
38699982
DOI
10.1002/anie.202405983
Knihovny.cz E-zdroje
- Klíčová slova
- On-surface synthesis, STM, XPS, photochemistry, semiconductor surfaces,
- Publikační typ
- časopisecké články MeSH
On-surface synthesis has become a prominent method for growing low-dimensional carbon-based nanomaterials on metal surfaces. However, the necessity of decoupling organic nanostructures from metal substrates to exploit their properties requires either transfer methods or new strategies to perform reactions directly on inert surfaces. The use of on-surface light-induced reactions directly on semiconductor/insulating surfaces represents an alternative approach to address these challenges. Here, exploring the photochemical activity of different organic molecules on a SnSe semiconductor surface under ultra-high vacuum, we present a novel on-surface light-induced reaction. The selective photodissociation of the anhydride group is observed, releasing CO and CO2. Moreover, we rationalize the relationship between the photochemical activity and the π-conjugation of the molecular core. The different experimental behaviour of two model anhydrides was elucidated by theoretical calculations, showing how the molecular structure influences the distribution of the excited states. Our findings open new pathways for on-surface synthesis directly on technologically relevant substrates.
CNR Istituto di Struttura della Materia via Fosso del Cavaliere 100 00133 Rome Italy
Empa Swiss Federal Laboratories for Materials Science and Technology 8600 Dübendorf Switzerland
Institute of Physics Czech Academy of Sciences Cukrovarnická 10 16200 Prague 6 Czech Republic
Institute of Physics Swiss Federal Institute of Technology Lausanne CH 1015 Lausanne Switzerland
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