The catalytic performance of phosphate-stabilized WOx-ZrO2 compositions in gas-phase glycerol dehydration has been investigated. Results show that varying WO3 concentrations direct the process towards either acrolein or allyl alcohol formation. Catalysts with low WOx content exhibit strong Lewis acid sites (Zr4+ and W6+), where these metal ions likely function as redox sites, facilitating glycerol hydrogenolysis to produce allyl alcohol. Higher WOx concentrations (exceeding 20 wt %) lead to the shielding of some W6+ and Zr4+ sites by polytungstate surface complexes, which are strong Brønsted acid sites. This alteration promotes glycerol dehydration through the removal of two water molecules, thereby shifting the selectivity towards acrolein formation.

Department of Catalytic Synthesis Based on Single Carbon Molecules L 5 Pysarzhevskii Institute of Physical Chemistry National Academy of Sciences of Ukraine Prospect Nauki 31 03039 Kyiv Ukraine

Department of Surface and Plasma Science Charles University 5 Holešovičkách 747 2 180 00 Prague 8 Czech Republic

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