In the past few years, aqueous zinc-metal batteries (ZMBs) have gained much attention and can be regarded as a potential alternative to lithium-metal batteries owing to their high safety, nature of abundance, and environmental sustainability. However, several challenges persist, including dendrite formation, corrosion, and unwanted side reactions, before ZMBs can be fully utilized in practical applications. To circumvent these issues, anode free zinc-metal batteries (AFZMBs) have emerged as a next-generation energy storage system. This review provides a comprehensive analysis of recent developments in AFZMBs, including their working mechanisms, advantages over conventional ZMBs, and the challenges for practical implementation. It also highlights the key strategies, including current collector modification, electrolyte engineering, and 3D printing techniques to enhance zinc deposition uniformity and cycling stability. The review also explores how 3D printing technology can revolutionize the design of advanced current collectors and zinc-rich cathodes, optimizing material utilization and enhancing battery performance. Finally, with a future perspective of AFZMBs is concluded, highlighting the need for further research to address existing bottlenecks and fully unlock their potential for next-generation energy storage.

Faculty of Electrical Engineering and Computer Science VSB Technical University of Ostrava 17 listopadu 2172 15 Ostrava 70800 Czech Republic

New Technologies Research Centre University of West Bohemia Univerzitní 8 Plzeň 30614 Czech Republic

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Chu S., Majumdar A., Nature 2012, 488, 294. PubMed

Larcher D., Tarascon J. M., Nat. Chem. 2015, 7, 19. PubMed

Bruce P. G., Freunberger S. A., Hardwick L. J., Tarascon J. M., Nat. Mater. 2012, 11, 19. PubMed

Li M., Lu J., Chen Z., Adv. Mater. 2018, 30, 1800561.

Kim T., Song W., Son D. Y., Ono L. K., Qi Y., J. Mater. Chem. A 2019, 7, 2942.

Dunn B., Kamath H., Tarascon J. M., Science 2011, 334, 928. PubMed

Tarascon J.‐M., Armand M., Nature 2001, 414, 359. PubMed

Liang Y., Dong H., Aurbach D., Yao Y., Nat. Energy 2020, 5, 646.

Chen R., Luo R., Huang Y., Wu F., Li L., Adv. Sci. 2016, 3, 1600051. PubMed PMC

De P., Pumera M., Small 2024, 2404227.

Nandi S., Pumera M., ChemSusChem 2024, 17, 202301434. PubMed

Xue X., Liu Z., Eisenberg S., Ren Q., Lin D., Coester E., Zhang H., Zhang J. Z., Wang X., Li Y., ACS Energy Lett. 2023, 8, 4658.

Ponrouch A., Bitenc J., Dominko R., Lindahl N., Johansson P., Palacin M. R., Energy Storage Mater. 2019, 20, 253.

Selvakumaran D., Pan A., Liang S., Cao G., J. Mater. Chem. A 2019,7, 18209.

Fang G., Zhou J., Pan A., Liang S., ACS Energy Lett. ACS Energy Lett. 2018, 10, 2480.

Zhang X., Hu J.‐P., Fu N., Zhou W.‐B., Liu B., Deng Q., Wu X.‐W., InfoMat 2022, 4, e12306.

Tang B., Shan L., Liang S., Zhou J., Energy Environ. Sci. 2019,12, 3288.

He W., Zuo S., Xu X., Zeng L., Liu L., Zhao W., Liu J., Mater. Chem. Front. 2021, 5, 2201.

Zhang T., Tang Y., Guo S., Cao X., Pan A., Fang G., Zhou J., Liang S., Energy Environ. Sci. 2020,13, 4625.

Neudecker B. J., Dudney N. J., Bates J. B., J. Electrochem. Soc. 2000, 147, 517.

Weber R., Genovese M., Louli A. J., Hames S., Martin C., Hill I. G., Dahn J. R., Nat. Energy 2019, 4, 683.

Xie Z., Wu Z., An X., Yue X., Wang J., Abudula A., Guan G., Energy Storage Mater. 2020, 32, 386.

Tang K., Tian L., Zhang Y., Xu Z. J., J. Mater. Chem. A 2024, 12, 16268.

Dahunsi O. J., Gao S., Kaelin J., Li B., Abdul Razak I. B., An B., Cheng Y., Nanoscale 2023, 15, 3255. PubMed

Hu Z., Liu L., Wang X., Zheng Q., Han C., Li W., Adv. Funct. Mater. 2024, 34, 2313823.

Zhu Q., Yu D., Chen J., Cheng L., Tang M., Wang Y., Li Y., Yang J., Wang H., Joule 2024, 8, 482.

Zhu Y., Cui Y., Alshareef H. N., Nano Lett. 2021, 21, 1446. PubMed

Lu C., Zhao F., Tao B., Wang Z., Wang Y., Sheng J., Tang G., Wang Y., Guo X., Li J., Wei L., Small 2024, 20, 2402025. PubMed

Tang M., Dong S., Wang J., Cheng L., Zhu Q., Li Y., Yang X., Guo L., Wang H., Nat. Commun. 2023, 14, 6006. PubMed PMC

Nie C., Wang G., Wang D., Wang M., Gao X., Bai Z., Wang N., Yang J., Xing Z., Dou S., Adv. Energy Mater. 2023, 13, 2300606.

Zhang H., Liu X., Li H., Hasa I., Passerini S., Angew. Chem., Int. Ed. 2021, 60, 598. PubMed PMC

Song J., Xu K., Liu N., Reed D., Li X., Mater. Today 2021, 45, 191.

Du W., Ang E. H., Yang Y., Zhang Y., Ye M., Li C. C., Energy Environ. Sci. 2020,13, 3330.

Zhu C., Li P., Xu G., Cheng H., Gao G., Coord. Chem. Rev. 2023, 485, 215142.

Chen J., Wang Y., Tian Z., Zhao J., Ma Y., Alshareef H. N., InfoMat 2023, 6, e12485.

Cui Y., Ju Z., Yu R., Du H., Zhang B., Wang Y., Yu G. C., ACS Mater. Lett. 2024, 6, 611.

Cao L., Li D., Pollard T., Deng T., Zhang B., Yang C., Chen L., Vatamanu J., Hu E., Hourwitz M. J., Ma L., Ding M., Li Q., Hou S., Gaskell K., Fourkas J. T., Yang X.‐Q., Xu K., Borodin O., Wang C., Nat. Nanotechnol. 2021, 16, 902. PubMed

Yao R., Qian L., Sui Y., Zhao G., Guo R., Hu S., Liu P., Zhu H., Wang F., Zhi C., Yang C., Adv. Energy Mater. 2022, 12, 2102780.

Chen Z., Li X., Wang D., Yang Q., Ma L., Huang Z., Liang G., Chen A., Guo Y., Dong B., Huang X., Yang C., Zhi C., Energy Environ. Sci. 2021,14, 3492.

Zhang S.‐J., Hao J., Luo D., Zhang P.‐F., Zhang B., Davey K., Lin Z., Qiao S.‐Z, Adv. Energy Mater. 2021, 11, 2102010.

Wang T., Sun J., Hua Y., Krishna B. N. V., Xi Q., Ai W., Yu J. S., Energy Storage Mater. 2022, 53, 273.

Wang Z., Huang J., Guo Z., Dong X., Liu Y., Wang Y., Xia Y., Joule 2019, 3, 1289.

Cao Q., Gao H., Gao Y., Yang J., Li C., Pu J., Du J., Yang J., Cai D., Pan Z., Guan C., Huang W., Adv. Funct. Mater. 2021, 31, 2103922.

Arnot D. J., Lim M. B., Bell N. S., Schorr N. B., Hill R. C., Meyer A., Cheng Y.‐T., Lambert T. N., Adv. Energy Mater. 2021, 11, 2101594.

Wang C., Wang D., Lv D., Peng H., Song X., Yang J., Qian Y., Adv. Energy Mater. 2023, 13, 2204388.

Wang T., Tang S., Xiao Y., Xiang W., Yu J. S., Energy Environ. Sci. 2025, 18, 545.

Zheng J., Zhao Q., Tang T., Yin J., Quilty C. D., Renderos G. D., Liu X., Deng Y., Wang L., Bock D. C., Jaye C., Zhang D., Takeuchi E. S., Takeuchi K. J., Marschilok A. C., Archer L. A., Science 2019, 366, 645. PubMed

Pande V., Viswanathan V., ACS Energy Lett. 2019, 4, 2952.

Yan K., Lu Z., Lee H.‐W., Xiong F., Hsu P.‐C., Li Y., Zhao J., Chu S., Cui Y., Nat. Energy 2016, 1.

Zhang N., Huang S., Yuan Z., Zhu J., Zhao Z., Niu Z., Angew. Chem., Int. Ed. 2021, 60, 2861. PubMed

Wang S.‐B., Ran Q., Yao R.‐Q., Shi H., Wen Z., Zhao M., Lang X.‐Y., Jiang Q., Nat. Commun. 2020, 1. PubMed PMC

Chen C., Guo R., Ganapathy S., Terpstra B., Wang H., Lei Z., Ooms F., Boshuizen B., Wagemaker M., Bannenberg L. J., Wang X., Small 2025, 2407226. PubMed

Chen H., Chen M., Zhou W., Han X., Liu B., Zhang W., Chen J., ACS Appl. Mater. Interfaces 2022, 14, 6876. PubMed

Zhang J., Mao L., Xia Z., Fan M., Deng Y., Chen Z., Adv. Funct. Mater. 2025, 35, 2412547.

Xie S., Li Y., Dong L., J. Energy Chem. 2023, 76, 32.

Xu K., Zheng X., Luo R., Sun J., Ma Y., Chen N., Wang M., Song L., Zhao Q., Chen W., Mater. Today Energy 2023, 34, 101284.

Ling W., Yang Q., Mo F., Lei H., Wang J., Jiao Y., Qiu Y., Chen T., Huang Y., Energy Storage Mater. 2022, 51, 453.

Li T. C., Lim Y. V., Xie X., Li X. L., Li G., Fang D., Li Y., Ang Y. S., Ang L. K., Yang H. Y., Small 2021, 17, 2101728. PubMed

Yu H., Zeng Y., Li N. W., Luan D., Yu L., Lou X. W, Sci. Adv. 2022, 8, eabm5766. PubMed PMC

Zheng X., Liu Z., Sun J., Luo R., Xu K., Si M., Kang J., Yuan Y., Liu S., Ahmad T., Jiang T., Chen N., Wang M., Xu Y., Chuai M., Zhu Z., Peng Q., Meng Y., Zhang K., Wang W., Chen W., Nat. Commun. 2023, 14, 76. PubMed PMC

An Y., Xu B., Tian Y., Shen H., Man Q., Liu X., Yang Y., Li M., Mater. Today 2023, 70, 93.

Li C., Cai K., Liang L., Dong J., Liu X., Cao N., Shao Q., Zang X., Energy Technol. 2022, 10, 2200150.

Jeong D. Y., Chang W. J., Jang S., Kim M., Kim Y., Kim B., Park W. I., J. Energy Storage 2024, 76,109791.

Jing Y., Meng X., Chen L., Yuan C., Wei H., ACS Appl. Mater. Interfaces 2024, 16, 18888. PubMed

Wei J., Zhang P., Sun J., Liu Y., Li F., Xu H., Ye R., Tie Z., Sun L., Jin Z., Chem. Soc. Rev. 2024, 53, 10335. PubMed

An Y., Tian Y., Zhang K., Liu Y., Liu C., Xiong S., Feng J., Qian Y., Adv. Funct. Mater. 2021, 31, 2101886.

Zhang Y., Wang L., Li Q., Hu B., Kang J., Meng Y., Zhao Z., Lu H., Nano‐Micro Lett. 2022, 14, 208. PubMed PMC

Shi W., Song Z., Zhang W., Lian S., Huang F., An Q., Li Q., Energy Environ. Sci. 2024, 17, 7372.

Meng Y., Wang M., Wang J., Huang X., Zhou X., Sajid M., Xie Z., Luo R., Zhu Z., Zhang Z., Khan N. A., Wang Y., Li Z., Chen W., Nat. Commun. 2024, 15, 8431. PubMed PMC

Li Y., Zheng X., Carlson E. Z., Xiao X., Chi X., Cui Y., Greenburg L. C., Zhang G., Zhang E., Liu C., Yang Y., Kim M. S., Feng G., Zhang P., Su H., Guan X., Zhou J., Wu Y., Xue Z., Li W., Bajdich M., Cui Y., Nat. Energy 2024, 9, 1350.

Ming F., Zhu Y., Huang G., Emwas A.‐H., Liang H., Cui Y., Alshareef H. N., J. Am. Chem. Soc. 2022, 144, 7160. PubMed

Xie J., Liang Z., Lu Y.‐C, Nat. Mater. 2020, 19, 1006. PubMed

Ciurduc D. E., de la Cruz C., Patil N., Mavrandonakis A., Marcilla R., Energy Storage Mater. 2022, 53, 532.

Li Y., Wang J., Wang S., Wang Y., Xu Y., Cheng L., Tang M., Wang G., Tian W., Huang W., Wang H., Energy Storage Mater. 2024, 66, 103245.

Yu H., He Z., Chen D., Liu P., He H., Jiang L., Chen Y., Chen L., Energy Rev. 2025, 4, 100107.

Jin C., Yang C., Xie L., Mi H., Yin H., Xu B., Guo F., Qiu J., Adv. Energy Mater. 2025, 15, 2402843.

Kim H.‐I., Lee K. M., Kim W.‐Y., Kweon S. H., Wang X., Zheng S., Kim S.‐H., Ha J. H., Kang S. J., Wu Z.‐S., Kwak S. K., Lee S.‐Y., Energy Environ. Sci. 2024, 17, 1961.

Liu C., Xie X., Lu B., Zhou J., Liang S., ACS Energy Lett. 2021, 6, 1015.

Xu Z., Zhang Y., Gou W., Liu M., Sun Y., Han X., Sun W., Li C., Chem. Commun. 2022, 58, 8145. PubMed

Browne M. P., Redondo E., Pumera M., Chem. Rev. 2020, 120, 2783. PubMed

Xue X., Lin D., Li Y., Small Struct. 2022, 3, 2200159.

Ambrosi A., Pumera M., Chem. Soc. Rev. 2016, 45, 2740. PubMed

Zhang F., Wei M., Viswanathan V. V., Swart B., Shao Y., Wu G., Zhou C., Nano Energy 2017, 40, 418.

Zhang G., Zhang X., Liu H., Li J., Chen Y., Duan H., Adv. Energy Mater. 2021, 11, 2003927.

Ma H., Tian X., Wang T., Hou S., Jin H., ACS Appl. Mater. Interfaces 2023, 15, 57049. PubMed

Wu B., Guo B., Chen Y., Mu Y., Qu H., Lin M., Bai J., Zhao T., Zeng L., Energy Storage Mater. 2023, 54, 75.

Ma H., Tian X., Wang T., Tang K., Liu Z., Hou S., Jin H., Cao G., Small 2021, 17, 2100746. PubMed

Lu Y., Wang Z., Li M., Li Z., Hu X., Xu Q., Wang Y., Liu H., Wang Y., Adv. Funct. Mater. 2023, 34, 2310966.

Tan P., Chen B., Xu H., Zhang H., Cai W., Ni M., Liu M., Shao, Energy Environ. Sci. 2017, 10, 2056.

Gao X., Zhang H., Liu X., Lu X., Carbon Energy. 2020, 2, 387.

Gao C., Wang J., Huang Y., Li Z., Zhang J., Kuang H., Chen S., Nie Z., Huang S., Li W., Li Y., Jin S., Pan Y., Long T., Luo J., Zhou H., Wang X., Nanoscale 2021, 13, 10100. PubMed

Zhang M., Yu P., Xiong K., Wang Y., Liu Y., Liang Y., Adv. Mater. 2022, 34, 2200860. PubMed

Wang W., Tang M., Zheng Z., Chen S., Adv. Energy Mater. 2019, 9, 1803628.

Zeng L., He J., Yang C., Luo D., Yu H., He H., Zhang C., Energy Storage Mater. 2023, 54, 469.

He H., Zeng L., Luo D., He J., Li X., Guo Z., Zhang C., Adv. Mater. 2023, 35, 2211498. PubMed

Yang H., Wan Y., Sun K., Zhang M., Wang C., He Z., Li Q., Wang N., Zhang Y., Hu H., Wu M., Adv. Funct. Mater. 2023, 33, 2215076.

Gao W., Michalicka J., Pumera M., Small 2022, 18, 2105572. PubMed

Tagliaferri S., Nagaraju G., Sokolikova M., Quintin‐Baxendale R., Mattevi C., Nanoscale Horiz. 2024, 9, 742. PubMed