Racemic 9,10-diketo[7]helicene was successfully separated into enantiomers using a reversible and stereoselective reaction with 2,2'-diamino-1,1'-binaphthalene with moderate yields but with remarkable purity (>99% de). The enantiomerically pure diketone was used as a convenient starting material for the preparation of helicene-based push-pull molecules, which incorporated aza-aryl acceptors and diarylaminophenylene donor groups in a single step. A series of six push-pull systems, along with three reference molecules without donors, were prepared and studied using UV/vis and fluorescence measurements, circular dichroism, and DFT calculations.

• Publication type
• Journal Article MeSH

Design and properties of a plasmonic modulator in situ tunable by electric field are presented. Our design comprises the creation of periodic surface pattern on the surface of an elastic polymer supported by a piezo-substrate by excimer laser irradiation and subsequent selective coverage by silver by tilted angle vacuum evaporation. The structure creation was confirmed by AFM and FIB-SEM techniques. An external electric field is used for fine control of the polymer pattern amplitude, which tends to decrease with increasing voltage. As a result, surface plasmon-polariton excitation is quenched, leading to the less pronounced structure of plasmon response. This quenching was checked using UV-Vis spectroscopy and SERS measurements, and confirmed by numerical simulation. All methods prove the proposed functionality of the structures enabling the creation smart plasmonic materials for a very broad range of advanced optical applications.

• Keywords
• LIPSS, SERS, modification, nanostructures, plasmon excitation, polymer, sensor, smart materials, thin layers,
• Publication type
• Journal Article MeSH