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Bioavailability of mercury in contaminated soils assessed by the diffusive gradient in thin film technique in relation to uptake by Miscanthus × giganteus

A. Ridošková, A. Pelfrêne, F. Douay, P. Pelcová, V. Smolíková, V. Adam,

. 2019 ; 38 (2) : 321-328. [pub] 20190108

Language English Country United States

Document type Journal Article, Research Support, Non-U.S. Gov't

Persistent link   https://www.medvik.cz/link/bmc19027931

We assessed the relationship between the diffusive gradient in thin film (DGT) technique using the new ion-exchange resin Ambersep GT74 and the uptake of mercury (Hg) by a model plant cultivated on metal-contaminated agricultural soils under greenhouse conditions. Based on the total Hg content, 0.37 to 1.17% of the Hg passed to the soil porewater from the solid phase, and 2.18 to 9.18% of the Hg is DGT-available. These results were confirmed by calculating the R value (the ratio of the concentrations of bioavailable Hg measured by DGT and soil solution), which illustrated the strong bonding of Hg to the solid phase of soil and its extremely low mobility. Only inorganic Hg2+ species were found in the metal-contaminated agricultural soils, as determined by a high-performance liquid chromatography-cold vapor atomic fluorescence spectrometry speciation analysis. The Hg was distributed in Miscanthus × giganteus organs in the following order for all sampling sites: roots (55-82%) > leaves (8-27%) > stems (7-16%) > rhizomes (4-7%). Environ Toxicol Chem 2019;38:321-328. © 2018 SETAC.

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$a Ridošková, Andrea $u Department of Chemistry and Biochemistry, Mendel University in Brno, Brno, Czech Republic. Central European Institute of Technology, University of Technology, Brno, Czech Republic.
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$a Pelcová, Pavlína $u Department of Chemistry and Biochemistry, Mendel University in Brno, Brno, Czech Republic.
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