Separation of enantiomeric triacylglycerols by chiral-phase HPLC
Jazyk angličtina Země Spojené státy americké Médium print-electronic
Typ dokumentu časopisecké články, práce podpořená grantem
- MeSH
- Chlorophyta chemie MeSH
- hmotnostní spektrometrie metody MeSH
- molekulární struktura MeSH
- nenasycené mastné kyseliny analýza chemie izolace a purifikace MeSH
- stereoizomerie MeSH
- tandemová hmotnostní spektrometrie metody MeSH
- triglyceridy analýza chemie MeSH
- vysokoúčinná kapalinová chromatografie metody normy MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- nenasycené mastné kyseliny MeSH
- triglyceridy MeSH
Liquid chromatography-atmospheric pressure chemical ionization mass spectrometry (LC-MS/APCI) with a chiral phase was used for separation of triacylglycerols (TAG) obtained either by organic synthesis or isolated from different algal species. We present chromatographic characteristics and tandem mass spectra of enantiomers and positional isomers (regioisomers) of C16, C18 and C20 polyunsaturated fatty acids. The retention time was found to depend on the structure of the given TAG, increasing with increasing number of double bonds and decreasing with increasing number of the carbons in TAG, with the exception of dieicosapentaenoyl-palmitoyl-glycerols.
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