Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host-guest complexation with γ-cyclodextrin
Status PubMed-not-MEDLINE Language English Country Great Britain, England Media print-electronic
Document type Journal Article
PubMed
31663544
DOI
10.1039/c9cc07678f
Knihovny.cz E-resources
- Publication type
- Journal Article MeSH
We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.
Department of Life Sciences and Chemistry Jacobs University Bremen 28759 Bremen Germany
Faculty of Chemical Technology University of Pardubice Studentská 95 532 10 Pardubice Czech Republic
Institute of Inorganic Chemistry Czech Academy of Sciences 25068 ŘeŽ Czech Republic
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