Nitroxide-mediated polymerization is now a mature technique, at 35 years of age. During this time, several variants have been developed: electron spin capture polymerization (ESCP), photoNMP (NMP2), chemically initiated NMP (CI-NMP), spin label NMP (SL-NMP), and plasmon-initiated NMP (PI-NMP). This mini-review is devoted to the features and applications of these variants.

Aix Marseille Univ CNRS ICR UMR 7273 Case 551 Avenue Escadrille Normandie Niemen 13397 Marseille Cedex 20 France

Department of Solid State Engineering University of Chemistry and Technology 16628 Prague Czech Republic

N N Vorozhtsov Novosibirsk Institute of Organic Chemistry Siberian Branch of Russian Academy of Sciences Pr Lavrentjeva 9 Novosibirsk 630090 Russia

Novosibirsk State University Pirogova str 2 Novosibirsk 630090 Russia

Research School of Chemistry and Applied Biomedical Sciences Tomsk Polytechnic University Lenin Ave 30 Tomsk Tomsk Oblast 634050 Russia

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