Modelling the Stiffness-Temperature Dependence of Resin-Rubber Blends Cured by High-Energy Electron Beam Radiation Using Global Search Genetic Algorithm

. 2020 Nov 11 ; 12 (11) : . [epub] 20201111

Status PubMed-not-MEDLINE Jazyk angličtina Země Švýcarsko Médium electronic

Typ dokumentu časopisecké články

Perzistentní odkaz   https://www.medvik.cz/link/pmid33187100

Grantová podpora
1/0589/17 Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
003TnUAD-4/2019 Kultúrna a Edukacná Grantová Agentúra MŠVVaŠ SR
002TnUAD-4/2019 Kultúrna a Edukacná Grantová Agentúra MŠVVaŠ SR

Modelling the influence of high-energy ionising radiation on the properties of materials with polymeric matrix using advanced artificial intelligence tools plays an important role in the research and development of new materials for various industrial applications. It also applies to effective modification of existing materials based on polymer matrices to achieve the desired properties. In the presented work, the effects of high-energy electron beam radiation with various doses on the dynamic mechanical properties of melamine resin, phenol-formaldehyde resin, and nitrile rubber blend have been studied over a wide temperature range. A new stiffness-temperature model based on Weibull statistics of the secondary bonds breaking during the relaxation transitions has been developed to quantitatively describe changes in the storage modulus with temperature and applied radiation dose until the onset of the temperature of the additional, thermally-induced polymerisation reactions. A global search real-coded genetic algorithm has been successfully applied to optimise the parameters of the developed model by minimising the sum-squared error. An excellent agreement between the modelled and experimental data has been found.

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. 2022 Feb 09 ; 14 (4) : . [epub] 20220209

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