"Activated Borane" - A Porous Borane Cluster Network as an Effective Adsorbent for Removing Organic Pollutants
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
20-04408S
Grantová Agentura České Republiky
19-05259S
Grantová Agentura České Republiky
PubMed
36017982
DOI
10.1002/chem.202201885
Knihovny.cz E-zdroje
- Klíčová slova
- activated borane, decaborane, gas adsorption, pollutant removal, porous polymer,
- Publikační typ
- časopisecké články MeSH
The unprecedented co-thermolysis of decaborane(14) (nido-B10 H14 ) and toluene results in a novel porous material (that we have named "activated borane") containing micropores between 1.0 and 1.5 nm in diameter and a specific surface area of 774 m2 g-1 (Ar, 87 K) that is thermally stable up to 1000 °C. Solid state 1 H, 11 B and 13 C MAS NMR, UV-vis and IR spectroscopies suggest an amorphous structure of borane clusters interconnected by toluene moieties in a ratio of about three toluene molecules for every borane cluster. In addition, the structure contains Lewis-acidic tri-coordinated boron sites giving it some unique properties. Activated borane displays high sorption capacity for pollutants such as sulfamethoxazole, tramadol, diclofenac and bisphenol A that exceed the capacity of commercially-available activated carbon. The consistency in properties for each batch made, and the ease of its synthesis, make activated borane a promising porous material worthy of broad attention.
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"Activated Borane": A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst
