Bi-magnetic core-shell spinel ferrite-based nanoparticles with different CoFe2O4 core size, chemical nature of the shell (MnFe2O4 and spinel iron oxide), and shell thickness were prepared using an efficient solvothermal approach to exploit the magnetic coupling between a hard and a soft ferrimagnetic phase for magnetic heat induction. The magnetic behavior, together with morphology, stoichiometry, cation distribution, and spin canting, were investigated to identify the key parameters affecting the heat release. General trends in the heating abilities, as a function of the core size, the nature and the thickness of the shell, were hypothesized based on this systematic fundamental study and confirmed by experiments conducted on the water-based ferrofluids.

Center for Functional Nanomaterials Brookhaven National Laboratory 735 Brookhaven Ave Upton NY 11973 USA

Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali Italy

Consorzio per la Promozione di Attività Universitarie Sulcis Iglesiente Italy

Department of Chemical and Geological Sciences University of Cagliari S S 554 bivio per Sestu 09042 Monserrato Italy

Department of Chemistry U Schiff University of Florence Via della Lastruccia 3 13 50019 Sesto Fiorentino Italy

Department of Condensed Matter Physics Charles University Ke Karlovu 5 12116 Prague 2 Czech Republic

Department of Inorganic Chemistry Charles University Hlavova 8 12800 Prague 2 Czech Republic

Department of Physics and Astronomy University of California Irvine CA 92697 USA

Istituto di Chimica dei Composti OrganoMetallici Consiglio Nazionale delle Ricerche Italy

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