Long-term leaching kinetics and solution chemistry of aqueous BaTiO3 powder suspensions: a numerical model supported experiment
Jazyk angličtina Země Anglie, Velká Británie Médium electronic
Typ dokumentu časopisecké články
PubMed
39480599
DOI
10.1039/d4tb01708k
Knihovny.cz E-zdroje
- MeSH
- kinetika MeSH
- koncentrace vodíkových iontů MeSH
- oxidy chemie MeSH
- prášky, zásypy, pudry * chemie MeSH
- roztoky MeSH
- sloučeniny barya * chemie MeSH
- suspenze chemie MeSH
- titan * chemie MeSH
- voda * chemie MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- barium titanate(IV) MeSH Prohlížeč
- oxidy MeSH
- prášky, zásypy, pudry * MeSH
- roztoky MeSH
- sloučeniny barya * MeSH
- suspenze MeSH
- titan * MeSH
- voda * MeSH
The advent of lead-free perovskite materials with favorable toxicity profiles has made them candidates for in vivo and environmental applications. However, their tendency to leach A-site cations raises concerns about toxicity, catalytic efficiency, and slurry properties. The present study investigates the long-term leaching kinetics of BaTiO3 powders over 31 days in aqueous solutions of varying pH levels. Using ICP-MS analysis and a numerical model based on the Unreacted Shrinking Core (USC) principle. The study extends the understanding of BaTiO3 stability beyond previously reported timeframes. The findings highlight the material's long-term stability, with implications for biomedical and environmental applications.
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