Photogeneration and Visualization of a Surface-Stabilized Dinitrene
Status PubMed-not-MEDLINE Language English Country Germany Media print-electronic
Document type Journal Article
Grant support
MSCA Fellowship CZ FZU I-CZ.02.01.01/00/22_010/0002906
Ministerstvo Školství, Mládeže a Tělovýchovy
e-INFRA CZ LM2018140
Ministerstvo Školství, Mládeže a Tělovýchovy
LM2023051
Ministerstvo Školství, Mládeže a Tělovýchovy
P 33527-N
Austrian Science Fund
I 5145-N
Austrian Science Fund
21-17194L
Grantová Agentura České Republiky
PubMed
39989376
PubMed Central
PMC12070354
DOI
10.1002/anie.202502640
Knihovny.cz E-resources
- Keywords
- azide, metal surface, nitrene, photochemistry, scanning probe microscopy,
- Publication type
- Journal Article MeSH
Nitrenes are known as key intermediates in various chemical reactions. Nitrene transfer reactions are particularly effective for synthesizing nitrogen-containing compounds, where metal catalysts play a crucial role in controlling nitrene reactivity and selectivity. In this study, we demonstrate the formation of a stable surface-supported dinitrene on Au(111) through UV irradiation of its diazide precursor, characterized by scanning probe techniques. The photoreaction mechanism is elucidated with wavelength-dependent experiments and time-dependent density functional theory calculations. Our findings present the first real-space visualization of a metal nitrene adsorbed on a surface, highlighting its potential in catalysis and surface functionalization.
Department of Physical Chemistry University of Graz Heinrichstraße 28 8010 Graz Austria
Institute of Physics Czech Academy of Sciences Cukrovarnická 10 16200 Prague 6 Czech Republic
Instituto de Ciencia de Materiales de Madrid CSIC Cantoblanco 28049 Madrid Spain
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