Unusual Scaffold Rearrangement in Polyaromatic Hydrocarbons Driven by Concerted Action of Single Gold Atoms on a Gold Surface
Status PubMed-not-MEDLINE Jazyk angličtina Země Německo Médium print-electronic
Typ dokumentu časopisecké články
Grantová podpora
21-39639L
Grantová Agentura České Republiky
20-13692X
Grantová Agentura České Republiky
CZ.02.1.01/0.0/0.0/16_019/0000754
Ministerstvo Školství, Mládeže a Tělovýchovy
LM2015042
Ministerstvo Školství, Mládeže a Tělovýchovy
LM2015085
Ministerstvo Školství, Mládeže a Tělovýchovy
PubMed
36239196
DOI
10.1002/anie.202208010
Knihovny.cz E-zdroje
- Klíčová slova
- (PAH) Polyaromatic Hydrocarbon, (SPM) Scanning Probe Microscopy, on-Surface Synthesis,
- Publikační typ
- časopisecké články MeSH
Chemical transformation of polyaromatic hydrocarbon (PAH) molecules following different reaction strategies has always been the focus of organic synthesis. In this work, we report the synthesis of a PAH molecule, formation of which consists of an unusual C-C bond cleavage accompanied by a complex π-conjugated molecular scaffold rearrangement. We demonstrate that the complex chemical transformation is steered by concerted motion of individual Au0 gold atoms on a supporting Au(111) surface. This observation underpins the importance of single-atom catalysis mediated by adatoms in on-surface synthesis as well as catalytic activity of single Au0 atoms facilitating cleavage of covalent carbon bonds.
Department of Organic Chemistry Charles University 128 00 Prague 2 Czech Republic
Institute of Physics of Czech Academy of Sciences 16200 Prague Czech Republic
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