Passive sampling techniques have been increasingly used to evaluate pollution of various environmental compartments. In many studies, fish and other aquatic biota have been monitored to assess the bioavailable fraction of pollutants. This review discusses the potential of two types of passive sampling devices (SPMD and Chemcatcher), which may serve as an efficient tool for monitoring of environmental pollutants, such as organochlorine pesticides (OCP), polychlorinated biphenyls (PCB) and polyaromatic hydrocarbons (PAH) in river waters, sediments and soil. Purification of SPMD extracts was performed by gel permeation chromatography (GPC). For identification and quantification GC/MS was used. Passive sampling devices are suitable tools for routine monitoring of environmental pollution enabling the examination of environmental matrices without repeated sampling and analyzing high water volumes.
Brominated flame retardants (BFRs) represented by polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecane (HBCD) together with major persistent organochlorine pollutants, polychlorinated biphenyls (PCBs) and selected organochlorine pesticides (OCPs), were determined in adipose tissue samples (n=98) obtained by liposuction of Czech subjects. Compared to other organochlorine pollutants (mostly PCBs and DDTs), levels of PBDE were lower by 2 orders of magnitude ranging from 0.2 to 54.3 ng/g lipid weight. PBDE congeners No. 47, 99, 153 and 183 were the most abundant constituting up to 90% of these pollutants in adipose tissue. The PBDEs content measured in this study was comparable with data reported in similar samples collected in Spain, Sweden, Belgium and Japan, whilst slightly lower than in the United States. Regarding PCBs, the dominating congeners were No. 138, 153 and 180 representing up to 90% of indicator congeners. The levels of PCBs were similar to those found in other European countries. While no age dependency was found for PBDEs, an increase of PCB and OCP levels with age was observed. Different exposure routes of donors were documented by the absence of the relationship between PCBs and OCPs.
- MeSH
- bromované uhlovodíky analýza MeSH
- dospělí MeSH
- financování organizované MeSH
- lidé středního věku MeSH
- lidé MeSH
- mladiství MeSH
- retardanty hoření analýza MeSH
- tuková tkáň chemie MeSH
- věkové faktory MeSH
- Check Tag
- dospělí MeSH
- lidé středního věku MeSH
- lidé MeSH
- mladiství MeSH
- mužské pohlaví MeSH
- ženské pohlaví MeSH
- Publikační typ
- srovnávací studie MeSH
- Geografické názvy
- Česká republika MeSH