Ag-decorated TiO2 nanostructured materials are promising photocatalysts. We used non-standard cryo-lyophilization and ArF laser ablation methods to produce TiO2 nanosheets and TiO2 nanostructured thin films decorated with Ag nanoparticles. Both methods have a common advantage in that they provide a single multiply twinned Ag(0) characterized by {111} twin boundaries. Advanced microscopy techniques and electron diffraction patterns revealed the formation of multiply twinned Ag(0) structures at elevated temperatures (500 °C and 800 °C). The photocatalytic activity was demonstrated by the efficient degradation of 4-chlorophenol and Total Organic Carbon removal using Ag-TiO2 nanosheets, because the multiply twinned Ag(0) served as an immobilized photocatalytically active center. Ag-TiO2 nanostructured thin films decorated with multiply twinned Ag(0) achieved improved photoelectrochemical water splitting due to the additional induction of a plasmonic effect. The photocatalytic properties of TiO2 nanosheets and TiO2 nanostructured thin films were correlated with the presence of defect-twinned structures formed from Ag(0) nanoparticles with a narrow size distribution, tuned to between 10 and 20 nm. This work opens up new possibilities for understanding the defects generated in Ag-TiO2 nanostructured materials and paves the way for connecting their morphology with their photocatalytic activity.
- Klíčová slova
- Ag(0) NPs, anatase, nanosheets, photocatalytic activity, thin films, twinned defects,
- Publikační typ
- časopisecké články MeSH
Understanding the molecular mechanisms governing nanoparticle-membrane interactions is of prime importance for drug delivery and biomedical applications. Neutron reflectometry (NR) experiments are combined with atomistic and coarse-grained molecular dynamics (MD) simulations to study the interaction between cationic gold nanoparticles (AuNPs) and model lipid membranes composed of a mixture of zwitterionic di-stearoyl-phosphatidylcholine (DSPC) and anionic di-stearoyl-phosphatidylglycerol (DSPG). MD simulations show that the interaction between AuNPs and a pure DSPC lipid bilayer is modulated by a free energy barrier. This can be overcome by increasing temperature, which promotes an irreversible AuNP incorporation into the lipid bilayer. NR experiments confirm the encapsulation of the AuNPs within the lipid bilayer at temperatures around 55 °C. In contrast, the AuNP adsorption is weak and impaired by heating for a DSPC-DSPG (3:1) lipid bilayer. These results demonstrate that both the lipid charge and the temperature play pivotal roles in AuNP-membrane interactions. Furthermore, NR experiments indicate that the (negative) DSPG lipids are associated with lipid extraction upon AuNP adsorption, which is confirmed by coarse-grained MD simulations as a lipid-crawling effect driving further AuNP aggregation. Overall, the obtained detailed molecular view of the interaction mechanisms sheds light on AuNP incorporation and membrane destabilization.
- Klíčová slova
- gold nanoparticles, lipid membranes, molecular dynamics simulations, nanotoxicity, neutron reflectometry,
- MeSH
- adsorpce MeSH
- biologický transport MeSH
- fosfatidylcholiny chemie metabolismus MeSH
- fosfatidylglyceroly chemie metabolismus MeSH
- hydrofobní a hydrofilní interakce MeSH
- kationty chemie farmakokinetika MeSH
- kovové nanočástice * chemie MeSH
- lipidové dvojvrstvy chemie metabolismus MeSH
- membránové lipidy chemie metabolismus MeSH
- povrchové vlastnosti MeSH
- simulace molekulární dynamiky MeSH
- teplota * MeSH
- zlato chemie farmakokinetika MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- fosfatidylcholiny MeSH
- fosfatidylglyceroly MeSH
- kationty MeSH
- lipidové dvojvrstvy MeSH
- membránové lipidy MeSH
- zlato MeSH
The interplay between spin, charge and orbital degrees of freedom has led to the development of spintronic devices such as spin-torque oscillators and spin-transfer torque magnetic random-access memories. In this development, spin pumping represents a convenient way to electrically detect magnetization dynamics. The effect originates from direct conversion of low-energy quantized spin waves in the magnet, known as magnons, into a flow of spins from the precessing magnet to adjacent leads. In this case, a secondary spin-charge conversion element, such as heavy metals with large spin Hall angle or multilayer layouts, is required to convert the spin current into a charge signal. Here, we report the experimental observation of charge pumping in which a precessing ferromagnet pumps a charge current, demonstrating direct conversion of magnons into high-frequency currents via the relativistic spin-orbit interaction. The generated electric current, unlike spin currents generated by spin-pumping, can be directly detected without the need of any additional spin-charge conversion mechanism. The charge-pumping phenomenon is generic and gives a deeper understanding of its reciprocal effect, the spin orbit torque, which is currently attracting interest for their potential in manipulating magnetic information.
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
