Supercapacitors offer a promising alternative to batteries, especially due to their excellent power density and fast charging rate capability. However, the cycling stability and material synthesis reproducibility need to be significantly improved to enhance the reliability and durability of supercapacitors in practical applications. Graphene acid (GA) is a conductive graphene derivative dispersible in water that can be prepared on a large scale from fluorographene. Here, we report a synthesis protocol with high reproducibility for preparing GA. The charging/discharging rate stability and cycling stability of GA were tested in a two-electrode cell with a sulfuric acid electrolyte. The rate stability test revealed that GA could be repeatedly measured at current densities ranging from 1 to 20 A g-1 without any capacitance loss. The cycling stability experiment showed that even after 60,000 cycles, the material kept 95.3% of its specific capacitance at a high current density of 3 A g-1. The findings suggested that covalent graphene derivatives are lightweight electrode materials suitable for developing supercapacitors with extremely high durability.

• Keywords
• cycling stability, graphene acid, pseudocapacitance, supercapacitor,
• Publication type
• Journal Article MeSH

Efficient heterogeneous catalysis of hydrogen oxidation reaction (HOR) by platinum group metal (PGM)-free catalysts in proton-exchange membrane (PEM) fuel cells represents a significant challenge toward the development of a sustainable hydrogen economy. Here, we show that graphene acid (GA) can be used as an electrode scaffold for the noncovalent immobilization of a bioinspired nickel bis-diphosphine HOR catalyst. The highly functionalized structure of this material and optimization of the electrode-catalyst assembly sets new benchmark electrocatalytic performances for heterogeneous molecular HOR, with current densities above 30 mA cm-2 at 0.4 V versus reversible hydrogen electrode in acidic aqueous conditions and at room temperature. This study also shows the great potential of GA for catalyst loading improvement and porosity management within nanostructured electrodes toward achieving high current densities with a noble-metal free molecular catalyst.

• Keywords
• PGM-free fuel cells, bio-inspired catalysis, graphenic acid, molecular HOR, molecular electrocatalysis, non-covalent catalyst immobilization,
• Publication type
• Journal Article MeSH