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Microwave preparation of carbon quantum dots with different surface modification
Vedran Milosavljevic, Amitava Moulick, Pavel Kopel, Vojtěch Adam, René Kizek
Jazyk angličtina Země Česko
Typ dokumentu práce podpořená grantem, srovnávací studie
NLK
Open Access Digital Library
od 2014-01-01
ROAD: Directory of Open Access Scholarly Resources
od 2014 do 2015
- MeSH
- fluorescence MeSH
- kvantové tečky * MeSH
- kyselina askorbová MeSH
- kyselina citronová MeSH
- mikrovlny MeSH
- polyethylenglykoly MeSH
- povidon MeSH
- povrchové vlastnosti * MeSH
- sérový albumin hovězí MeSH
- spektrofotometrie statistika a číselné údaje MeSH
- techniky syntetické chemie MeSH
- teplota MeSH
- uhlík * MeSH
- Publikační typ
- práce podpořená grantem MeSH
- srovnávací studie MeSH
Carbon quantum dots (CQDs) have great potential to be utilized as an optical sensing probe due to its unique photoluminescence and less toxic properties. This work reports a simple and novel synthesis method of carbon dots via direct acid hydrolysis in presence of polyethylene glycol (PEG), polyvinylpyrrolidone (PVP) and bovine serum albumin protein (BSA). In this study, fluorescent CQDs were synthesized by using citric acid and ascorbic acid as the source of carbon precursors, which was covered with polyethylene glycol (PEG), polyvinylpyrrolidone (PVP) and with bovine serum albumin (BSA), by microwave irradiation. Furthermore, the synthesis parameters as power, reaction time and temperature were studied and quality of prepared CQDs were investigated by spectral methods. Short reaction time (20 min) and temperature from 120 ºC to 140 ºC under microwave irradiation are sufficient to prepare luminescence carbon quantum dots. Absorption spectra and photoluminescence spectra were measured to characterize prepared dots in water solution. The photoluminescence spectra of CQDs doped with different protection compound show the different luminescent and excitation wavelengths starting from 330 nm to 430 nm. Importantly, these CQDs are demonstrated to be excellent bioimaging agents and fluorescent ink due to their stable emission, well dispersibility, low toxicity, long emission life time, and good compatibility with different macromolecules.
Středoevropský technologický institut Vysoké učení technické v Brně
Ústav chemie a biochemie Agronomická fakulta Mendelova univerzita v Brně
Literatura
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- $a Carbon quantum dots (CQDs) have great potential to be utilized as an optical sensing probe due to its unique photoluminescence and less toxic properties. This work reports a simple and novel synthesis method of carbon dots via direct acid hydrolysis in presence of polyethylene glycol (PEG), polyvinylpyrrolidone (PVP) and bovine serum albumin protein (BSA). In this study, fluorescent CQDs were synthesized by using citric acid and ascorbic acid as the source of carbon precursors, which was covered with polyethylene glycol (PEG), polyvinylpyrrolidone (PVP) and with bovine serum albumin (BSA), by microwave irradiation. Furthermore, the synthesis parameters as power, reaction time and temperature were studied and quality of prepared CQDs were investigated by spectral methods. Short reaction time (20 min) and temperature from 120 ºC to 140 ºC under microwave irradiation are sufficient to prepare luminescence carbon quantum dots. Absorption spectra and photoluminescence spectra were measured to characterize prepared dots in water solution. The photoluminescence spectra of CQDs doped with different protection compound show the different luminescent and excitation wavelengths starting from 330 nm to 430 nm. Importantly, these CQDs are demonstrated to be excellent bioimaging agents and fluorescent ink due to their stable emission, well dispersibility, low toxicity, long emission life time, and good compatibility with different macromolecules.
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