Bimetallic alloy nanostructures have garnered much attention due to their unique performances in catalytic processes. However, decline in catalytic activity over the life span has been a protracted limitation, ascribed largely to the aggregation or dissociation of particles and still remains a challenge for manufacturing bimetallic nanostructures of sufficient stability. Herein, a surfactant- and solvent-free greener strategy is presented for the fabrication of bimetallic palladium-platinum (PdPt) nanotubes (NTs), deploying lipid tubules as template and ascorbic acid as a reducing agent; the ensuing NTs comprise crystalline tubal nanostructures of ∼12 μm length, ∼500 nm cross-sectional diameter, and ∼57 nm tube wall thickness. When used for the catalytic reduction of p-nitrophenol (PNP), the PdPt NTs delivered improved kinetic apparent rate constants (kapp) compared to Pt NTs (0.5 min-1vs. 0.2 min-1). Moreover, the NTs demonstrated high stability when used over multiple catalytic cycles thus opening up new potential routes for the fabrication of alloy NTs using lipid tubules as templates.

Regional Centre of Advanced Technologies and Materials Faculty of Science Palacky University Šlechtitelů 27 783 71 Olomouc Czech Republic

School of Chemical Engineering and Technology Harbin Institute of Technology 92 West Da Zhi Street Harbin 150001 China

School of Environment Tsinghua University Beijing 100084 China

School of Environment Tsinghua University Beijing 100084 China; School of Chemical Engineering and Technology Harbin Institute of Technology 92 West Da Zhi Street Harbin 150001 China

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The Use of a Biopolymer Conjugate for an Eco-Friendly One-Pot Synthesis of Palladium-Platinum Alloys