Alkynylation of graphene via the Sonogashira C-C cross-coupling reaction on fluorographene
Status PubMed-not-MEDLINE Language English Country Great Britain, England Media print
Document type Journal Article
PubMed
30620024
PubMed Central
PMC6350624
DOI
10.1039/c8cc08492k
Knihovny.cz E-resources
- Publication type
- Journal Article MeSH
We report successful grafting of alkynyl groups onto graphene via the Sonogashira reaction between fluorographene and terminal alkynes. Theoretical calculations revealed that fluorographene can efficiently bind and oxidize the palladium catalyst on electrophilic sites activated by fluorine atoms. This paves the way towards conductive and mechanically robust 3D covalent networks.
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