Single-atom catalysts (SACs) based on graphene derivatives are an emerging and growing class of materials functioning as two-dimensional (2D) metal-coordination scaffolds with intriguing properties. Recently, owing to the rich chemistry of fluorographene, new avenues have opened toward graphene derivatives with selective, spacer-free, and dense functionalization, acting as in-plane or out-of-plane metal coordination ligands. The particular structural features give rise to intriguing phenomena occurring between the coordinated metals and the graphene backbone. These include redox processes, charge transfer, emergence, and stabilization of rare or otherwise unstable metal valence states, as well as metal-support and metal-metal synergism. The vast potential of such systems has been demonstrated as enzyme mimics for cooperative mixed-valence SACs, ethanol fuel cells, and CO2 fixation; however, it is anticipated that their impact will further expand toward diverse fields, e.g., advanced organic transformations, electrochemical energy storage, and energy harvesting.

Centre of Energy and Environmental Technologies Nanotechnology Centre VŠB Technical University of Ostrava 17 listopadu 2172 15 708 00 Ostrava Poruba Czech Republic

Department of Physical Chemistry Palacký University Olomouc 17 listopadu 12 771 46 Olomouc Czech Republic

IT4Innovations VŠB Technical University of Ostrava 17 listopadu 2172 15 708 00 Ostrava Poruba Czech Republic

Regional Centre of Advanced Technologies and Materials Czech Advanced Technology and Research Institute Palacký University Olomouc Šlechtitelů 27 783 71 Olomouc Czech Republic

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Gawande M. B. Fornasiero P. Zbořil R. ACS Catal. 2020;10:2231–2259.

Yang X.-F. Wang A. Qiao B. Li J. Liu J. Zhang T. Acc. Chem. Res. 2013;46:1740–1748. PubMed

Liang S. Hao C. Shi Y. ChemCatChem. 2015;7:2559–2567.

Sultan S. Tiwari J. N. Singh A. N. Zhumagali S. Ha M. Myung C. W. Thangavel P. Kim K. S. Adv. Energy Mater. 2019;9:1900624.

Cheng N. Zhang L. Doyle-Davis K. Sun X. Electrochem. Energy Rev. 2019;2:539–573.

Tiwari J. N. Singh A. N. Sultan S. Kim K. S. Adv. Energy Mater. 2020;10:2000280.

Wang X. Zhang Y. Wu J. Zhang Z. Liao Q. Kang Z. Zhang Y. Chem. Rev. 2022;122:1273–1348. PubMed

Ren S. Yu Q. Yu X. Rong P. Jiang L. Jiang J. Sci. China Mater. 2020;63:903–920.

Wang J. Li Z. Wu Y. Li Y. Adv. Mater. 2018;30:1801649. PubMed

Qi K. Chhowalla M. Voiry D. Mater. Today. 2020;40:173–192.

Georgakilas V. Perman J. A. Tucek J. Zboril R. Chem. Rev. 2015;115:4744–4822. PubMed

Bakandritsos A. Kadam R. G. Kumar P. Zoppellaro G. Medved’ M. Tuček J. Montini T. Tomanec O. Andrýsková P. Drahoš B. Varma R. S. Otyepka M. Gawande M. B. Fornasiero P. Zbořil R. Adv. Mater. 2019;31:1900323. PubMed

Yan C. Li H. Ye Y. Wu H. Cai F. Si R. Xiao J. Miao S. Xie S. Yang F. Li Y. Wang G. Bao X. Energy Environ. Sci. 2018;11:1204–1210.

Ha M. Kim D. Y. Umer M. Gladkikh V. Myung C. W. Kim K. S. Energy Environ. Sci. 2021;14:3455–3468.

Fei H. Dong J. Feng Y. Allen C. S. Wan C. Volosskiy B. Li M. Zhao Z. Wang Y. Sun H. An P. Chen W. Guo Z. Lee C. Chen D. Shakir I. Liu M. Hu T. Li Y. Kirkland A. I. Duan X. Huang Y. Nat. Catal. 2018;1:63–72.

Elias D. C. Nair R. R. Mohiuddin T. M. G. Morozov S. V. Blake P. Halsall M. P. Ferrari A. C. Boukhvalov D. W. Katsnelson M. I. Geim A. K. Novoselov K. S. Science. 2009;323:610–613. PubMed

Zbořil R. Karlický F. Bourlinos A. B. Steriotis T. A. Stubos A. K. Georgakilas V. Šafářová K. Jančík D. Trapalis C. Otyepka M. Small. 2010;6:2885–2891. PubMed PMC

Nair R. R. Ren W. Jalil R. Riaz I. Kravets V. G. Britnell L. Blake P. Schedin F. Mayorov A. S. Yuan S. Katsnelson M. I. Cheng H.-M. Strupinski W. Bulusheva L. G. Okotrub A. V. Grigorieva I. V. Grigorenko A. N. Novoselov K. S. Geim A. K. Small. 2010;6:2877–2884. PubMed

Chua C. K. Ambrosi A. Pumera M. Chem. Commun. 2012;48:5376–5378. PubMed

Georgakilas V. Bourlinos A. B. Zboril R. Steriotis T. A. Dallas P. Stubos A. K. Trapalis C. Chem. Commun. 2010;46:1766–1768. PubMed

Sarkar S. Bekyarova E. Niyogi S. Haddon R. C. J. Am. Chem. Soc. 2011;133:3324–3327. PubMed

Economopoulos S. P. Rotas G. Miyata Y. Shinohara H. Tagmatarchis N. ACS Nano. 2010;4:7499–7507. PubMed

Liu J.-B. Gong H.-S. Ye G.-L. Fei H.-L. Rare Met. 2022;41:1703–1726.

Kovtyukhova N. I. Ollivier P. J. Martin B. R. Mallouk T. E. Chizhik S. A. Buzaneva E. V. Gorchinskiy A. D. Chem. Mater. 1999;11:771–778.

Erickson K. Erni R. Lee Z. Alem N. Gannett W. Zettl A. Adv. Mater. 2010;22:4467–4472. PubMed

Stankovich S. Dikin D. A. Piner R. D. Kohlhaas K. A. Kleinhammes A. Jia Y. Wu Y. Nguyen S. T. Ruoff R. S. Carbon. 2007;45:1558–1565.

Dubecký M. Otyepková E. Lazar P. Karlický F. Petr M. Čépe K. Banáš P. Zbořil R. Otyepka M. J. Phys. Chem. Lett. 2015;6:1430–1434. PubMed

Matochová D. Medved’ M. Bakandritsos A. Steklý T. Zbořil R. Otyepka M. J. Phys. Chem. Lett. 2018;9:3580–3585. PubMed PMC

Chronopoulos D. D. Bakandritsos A. Pykal M. Zbořil R. Otyepka M. Appl. Mater. Today. 2017;9:60–70. PubMed PMC

Mazánek V. Jankovský O. Luxa J. Sedmidubský D. Janoušek Z. Šembera F. Mikulics M. Sofer Z. Nanoscale. 2015;7:13646–13655. PubMed

Robinson J. T. Burgess J. S. Junkermeier C. E. Badescu S. C. Reinecke T. L. Perkins F. K. Zalalutdniov M. K. Baldwin J. W. Culbertson J. C. Sheehan P. E. Snow E. S. Nano Lett. 2010;10:3001–3005. PubMed

Jeon K.-J. Lee Z. Pollak E. Moreschini L. Bostwick A. Park C.-M. Mendelsberg R. Radmilovic V. Kostecki R. Richardson T. J. Rotenberg E. ACS Nano. 2011;5:1042–1046. PubMed

Tahara K. Iwasaki T. Furuyama S. Matsutani A. Hatano M. Appl. Phys. Lett. 2013;103:143106.

Ho K.-I. Liao J.-H. Huang C.-H. Hsu C.-L. Zhang W. Lu A.-Y. Li L.-J. Lai C.-S. Su C.-Y. Small. 2014;10:989–997. PubMed

Chen M. Zhou H. Qiu C. Yang H. Yu F. Sun L. Nanotechnology. 2012;23:115706. PubMed

Yang H. Chen M. Zhou H. Qiu C. Hu L. Yu F. Chu W. Sun S. Sun L. J. Phys. Chem. C. 2011;115:16844–16848.

Lee W. H. Suk J. W. Chou H. Lee J. Hao Y. Wu Y. Piner R. Akinwande D. Kim K. S. Ruoff R. S. Nano Lett. 2012;12:2374–2378. PubMed

Zhu M. Xie X. Guo Y. Chen P. Ou X. Yu G. Liu M. Phys. Chem. Chem. Phys. 2013;15:20992–21000. PubMed

Vizintin A. Lozinšek M. Chellappan R. K. Foix D. Krajnc A. Mali G. Drazic G. Genorio B. Dedryvère R. Dominko R. Chem. Mater. 2015;27:7070–7081.

Huang X. Liu Q. Huang X. Nie Z. Ruan T. Du Y. Jiang G. Anal. Chem. 2017;89:1307–1314. PubMed

Javaid S. Myung C. W. Pourasad S. Rakshit B. Kim K. S. Lee G. J. Mater. Chem. A. 2018;6:18635–18640.

Yang Z. Wang L. Sun W. Li S. Zhu T. Liu W. Liu G. Appl. Surf. Sci. 2017;401:146–155.

Bakandritsos A. Pykal M. Błoński P. Jakubec P. Chronopoulos D. D. Poláková K. Georgakilas V. Čépe K. Tomanec O. Ranc V. Bourlinos A. B. Zbořil R. Otyepka M. ACS Nano. 2017;11:2982–2991. PubMed PMC

Kadam R. G. Zhang T. Zaoralová D. Medveď M. Bakandritsos A. Tomanec O. Petr M. Zhu Chen J. Miller J. T. Otyepka M. Zbořil R. Asefa T. Gawande M. B. Small. 2021;17:2006477. PubMed

Blanco M. Agnoli S. Granozzi G. Isr. J. Chem. 2022;62:e202100118.

Langer R. Fako E. Błoński P. Vavrečka M. Bakandritsos A. Otyepka M. López N. Appl. Mater. Today. 2020;18:100462.

Zaoralová D. Mach R. Lazar P. Medveď M. Otyepka M. Adv. Mater. Interfaces. 2021;8:2001392.

Blanco M. Mosconi D. Tubaro C. Biffis A. Badocco D. Pastore P. Otyepka M. Bakandritsos A. Liu Z. Ren W. Agnoli S. Granozzi G. Green Chem. 2019;21:5238–5247.

Nair R. R. Sepioni M. Tsai I.-L. Lehtinen O. Keinonen J. Krasheninnikov A. V. Thomson T. Geim A. K. Grigorieva I. V. Nat. Phys. 2012;8:199–202. PubMed

Medveď M. Zoppellaro G. Ugolotti J. Matochová D. Lazar P. Pospíšil T. Bakandritsos A. Tuček J. Zbořil R. Otyepka M. Nanoscale. 2018;10:4696–4707. PubMed PMC

Liu Y. Noffke B. W. Gao X. Lozovyj Y. Cui Y. Fu Y. Raghavachari K. Siedle A. R. Li L. Phys. Chem. Chem. Phys. 2018;20:14287–14290. PubMed

Whitener K. E. Stine R. Robinson J. T. Sheehan P. E. J. Phys. Chem. C. 2015;119:10507–10512.

Chronopoulos D. D. Bakandritsos A. Lazar P. Pykal M. Čépe K. Zbořil R. Otyepka M. Chem. Mater. 2017;29:926–930. PubMed PMC

Mazánek V. Libánská A. Šturala J. Bouša D. Sedmidubský D. Pumera M. Janoušek Z. Plutnar J. Sofer Z. Chem. – Eur. J. 2017;23:1956–1964. PubMed

Lai W. Liu J. Luo L. Wang X. He T. Fan K. Liu X. Chem. Commun. 2018;54:10168–10171. PubMed

Huang F. Li Y. Liu X. Lai W. Fan K. Liu X. Wang X. Chem. Commun. 2021;57:351–354. PubMed

Chronopoulos D. D. Medved’ M. Błoński P. Nováček Z. Jakubec P. Tomanec O. Bakandritsos A. Novotná V. Zbořil R. Otyepka M. Chem. Commun. 2019;55:1088–1091. PubMed PMC

Tuček J. Holá K. Bourlinos A. B. Błoński P. Bakandritsos A. Ugolotti J. Dubecký M. Karlický F. Ranc V. Čépe K. Otyepka M. Zbořil R. Nat. Commun. 2017;8:14525. PubMed PMC

Zhao F.-G. Pan B. Kong Y.-T. Dong L. Hu C.-M. Sang Y.-J. Zhou X. Zuo B. Dong X. Li B. Li W.-S. Adv. Mater. Interfaces. 2019;6:1801699.

Zaoralová D. Hrubý V. Šedajová V. Mach R. Kupka V. Ugolotti J. Bakandritsos A. Medved’ M. Otyepka M. ACS Sustainable Chem. Eng. 2020;8:4764–4772.

Šedajová V. Bakandritsos A. Błoński P. Medveď M. Langer R. Zaoralová D. Ugolotti J. Dzíbelová J. Jakubec P. Kupka V. Otyepka M. Energy Environ. Sci. 2022;15:740–748. PubMed PMC

Tantis I. Bakandritsos A. Zaoralová D. Medveď M. Jakubec P. Havláková J. Zbořil R. Otyepka M. Adv. Funct. Mater. 2021;31:2101326.

Bosch-Navarro C. Walker M. Wilson N. R. Rourke J. P. J. Mater. Chem. C. 2015;3:7627–7631.

Stine R. Ciszek J. W. Barlow D. E. Lee W.-K. Robinson J. T. Sheehan P. E. Langmuir. 2012;28:7957–7961. PubMed

Fan K. Liu X. Liu Y. Li Y. Chen Y. Meng Y. Liu X. Feng W. Luo L. Carbon. 2020;167:826–834.

Barès H. Bakandritsos A. Medveď M. Ugolotti J. Jakubec P. Tomanec O. Kalytchuk S. Zbořil R. Otyepka M. Carbon. 2019;145:251–258.

Chronopoulos D. D. Medveď M. Potsi G. Tomanec O. Scheibe M. Otyepka M. Chem. Commun. 2020;56:1936–1939. PubMed

Siedle A. R. Losovyj Y. Karty J. A. Chen D. Chatterjee K. Carta V. Stein B. D. Werner-Zwanziger U. J. Phys. Chem. C. 2021;125:10326–10333.

Chen X. Fan K. Liu Y. Li Y. Liu X. Feng W. Wang X. Adv. Mater. 2022;34:2101665. PubMed

Zoppellaro G. Bakandritsos A. Tuček J. Błoński P. Susi T. Lazar P. Bad'ura Z. Steklý T. Opletalová A. Otyepka M. Zbořil R. Adv. Mater. 2019;31:1902587. PubMed

Vermisoglou E. C. Jakubec P. Bakandritsos A. Pykal M. Talande S. Kupka V. Zbořil R. Otyepka M. Chem. Mater. 2019;31:4698–4709. PubMed PMC

Vermisoglou E. C. Jakubec P. Bakandritsos A. Kupka V. Pykal M. Šedajová V. Vlček J. Tomanec O. Scheibe M. Zbořil R. Otyepka M. ChemSusChem. 2021;14:3904–3914. PubMed PMC

Stathis A. Stavrou M. Papadakis I. Bakandritsos A. Steklý T. Otyepka M. Couris S. Adv. Photonics Res. 2020;1:2000014.

Urbanová V. Holá K. Bourlinos A. B. Čépe K. Ambrosi A. Loo A. H. Pumera M. Karlický F. Otyepka M. Zbořil R. Adv. Mater. 2015;27:2305–2310. PubMed

Sturala J. Hermanová S. Artigues L. Sofer Z. Pumera M. Nanoscale. 2019;11:10695–10701. PubMed

Lazar P. Chua C. K. Holá K. Zbořil R. Otyepka M. Pumera M. Small. 2015;11:3790–3796. PubMed

Panáček D. Hochvaldová L. Bakandritsos A. Malina T. Langer M. Belza J. Martincová J. Večeřová R. Lazar P. Poláková K. Kolařík J. Válková L. Kolář M. Otyepka M. Panáček A. Zbořil R. Adv. Sci. 2021;8:2003090. PubMed PMC

Pykal M. Vondrák M. Šrejber M. Tantis I. Mohammadi Sigarikar E. Bakandritsos A. Medveď M. Otyepka M. Appl. Surf. Sci. 2022:153792.

Kolařík J. Bakandritsos A. Bad'ura Z. Lo R. Zoppellaro G. Kment Š. Naldoni A. Zhang Y. Petr M. Tomanec O. Filip J. Otyepka M. Hobza P. Zbořil R. ACS Nano. 2021;15:3349–3358. PubMed

Šedajová V. Jakubec P. Bakandritsos A. Ranc V. Otyepka M. Nanomaterials. 2020;10:1731. PubMed PMC

Obraztsov I. Bakandritsos A. Šedajová V. Langer R. Jakubec P. Zoppellaro G. Pykal M. Presser V. Otyepka M. Zbořil R. Adv. Energy Mater. 2022;12:2103010.

Seelajaroen H. Bakandritsos A. Otyepka M. Zbořil R. Sariciftci N. S. ACS Appl. Mater. Interfaces. 2020;12:250–259. PubMed PMC

Flauzino J. M. R. Nguyen E. P. Yang Q. Rosati G. Panáček D. Brito-Madurro A. G. Madurro J. M. Bakandritsos A. Otyepka M. Merkoçi A. Biosens. Bioelectron. 2022;195:113628. PubMed

Bakandritsos A. Chronopoulos D. D. Jakubec P. Pykal M. Čépe K. Steriotis T. Kalytchuk S. Petr M. Zbořil R. Otyepka M. Adv. Funct. Mater. 2018;28:1801111.

Mosconi D. Blanco M. Gatti T. Calvillo L. Otyepka M. Bakandritsos A. Menna E. Agnoli S. Granozzi G. Carbon. 2019;143:318–328.

Ma B. Blanco M. Calvillo L. Chen L. Chen G. Lau T.-C. Dražić G. Bonin J. Robert M. Granozzi G. J. Am. Chem. Soc. 2021;143:8414–8425. PubMed

Reuillard B. Blanco M. Calvillo L. Coutard N. Ghedjatti A. Chenevier P. Agnoli S. Otyepka M. Granozzi G. Artero V. ACS Appl. Mater. Interfaces. 2020;12:5805–5811. PubMed PMC

Zhuo H.-Y. Zhang X. Liang J.-X. Yu Q. Xiao H. Li J. Chem. Rev. 2020;120:12315–12341. PubMed

Wang J. Kong H. Zhang J. Hao Y. Shao Z. Ciucci F. Prog. Mater. Sci. 2021;116:100717.

Zhao C.-X. Li B.-Q. Liu J.-N. Zhang Q. Angew. Chem., Int. Ed. 2021;60:4448–4463. PubMed

Zhang H. Liu G. Shi L. Ye J. Adv. Energy Mater. 2018;8:1701343.

Navrátil J. Błoński P. Otyepka M. Nanotechnology. 2021;32:230001. PubMed

Li Y. Wang X. Wang W. Qin R. Lai W. Ou A. Liu Y. Liu X. J. Phys. Chem. C. 2019;123:584–592.

Liu Y. Shen Y. Sun L. Li J. Liu C. Ren W. Li F. Gao L. Chen J. Liu F. Sun Y. Tang N. Cheng H.-M. Du Y. Nat. Commun. 2016;7:10921. PubMed PMC

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