Currently, non-biodegradable oil-based plastics are gradually being replaced by bio-based biodegradable plastics to prevent the formation of microplastics. For biodegradable materials to decompose completely, however, they require specific conditions that are rarely met in ecosystems. Paradoxically, this may lead to the fast production of microplastics from biodegradable materials, i.e. micro-bioplastics. Until recently, the scientific focus has been solely on the estimation of conventional microplastics. As a result, there is a lack of analytical methods for determining the amount of micro-bioplastics in soil. In this review, we address this problem by summarising sample pre-treatments and analytical techniques suitable for the determination of conventional microplastics, which serve as inspiration for the determination of micro-bioplastics from polyhydroxybutyrates, polylactic acid and polybutylene adipate terephthalate in soil. The analytical techniques include both pyrolysis-based techniques, i.e. thermoanalytical and non-thermoanalytical approaches including sample pre-separation and respective detection limits. We conclude that due to the incomplete knowledge of the production rate of micro-bioplastics, fate, sorption properties and toxicity, it is necessary to develop and validate a rapid and suitable method for their determination. Indeed, the use of thermoanalytical approaches seems to be the most promising strategy. Furthermore, we suggest how the development and analysis of micro-bioplastics should be addressed in future research.

iES Landau Institute for Environmental Sciences Group of Environmental and Soil Chemistry University of Koblenz Landau Fortstraße 7 76829 Landau Germany

Institute of Chemistry and Technology of Environmental Protection Faculty of Chemistry Brno University of Technology Purkyňova 118 612 00 Brno Czech Republic

Institute of Material Science Faculty of Chemistry Brno University of Technology Purkyňova 118 612 00 Brno Czech Republic

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