Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction
Language English Country United States Media print-electronic
Document type Journal Article, Research Support, Non-U.S. Gov't
- MeSH
- Anions chemistry MeSH
- Chlorides * chemistry MeSH
- Crown Ethers * MeSH
- Lipid Bilayers chemistry MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- Anions MeSH
- Chlorides * MeSH
- Crown Ethers * MeSH
- Lipid Bilayers MeSH
Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid-liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers.
Department of Chemistry Faculty of Science Masaryk University Kamenice 5 625 00 Brno Czech Republic
Department of Chemistry Loughborough University Epinal Way Loughborough LE11 3TU U K
RECETOX Faculty of Science Masaryk University Kamenice 5 625 00 Brno Czech Republic
References provided by Crossref.org
Substituent effects of fluorinated bambusurils on their anion transport
Anion Transport by Bambusuril-Bile Acid Conjugates: Drastic Effect of the Cholesterol Content
Synthesis of Enantiomerically Pure Bambus[6]urils Utilizing Orthogonal Protection of Glycolurils