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Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction

. 2022 Aug 05 ; 87 (15) : 9829-9838. [epub] 20220721

Language English Country United States Media print-electronic

Document type Journal Article, Research Support, Non-U.S. Gov't

Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid-liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers.

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