Lithium-sulphur batteries attract increasing interest due to their high theoretical specific capacity, advantageous economy, and "eco-friendliness". In this study, a metal-organic framework (MOF) GaTCPP containing a porphyrinic base ligand was used as a conductive additive for sulphur. GaTCPP was synthesized, characterized, and post-synthetically modified by the transition metal ions (Co2+/Ni2+). The doping of GaTCPP ensured an increase in the carbon dioxide adsorption capacities, which were measured under different conditions. Post-synthetic modification of GaTCPP with Co2+/Ni2+ ions has been shown to increase carbon dioxide storage capacity from 22.8 wt% for unmodified material to 23.1 wt% and 26.5 wt% at 0 °C and 1 bar for Co2+ and Ni2+-doped analogues, respectively. As a conductive part of cathode material, MOFs displayed successful sulphur capture and encapsulation proven by stable charge/discharge cycle performances, high-capacity retention, and coulombic efficiency. The electrodes with pristine GaTCPP showed a discharge capacity of 699 mA h g-1 at 0.2C in the fiftieth cycle. However, the doping of GaTCPP by Ni2+ has a positive impact on the electrochemical properties, the capacity increased to 778 mA h g-1 in the fiftieth cycle at 0.2C.

Department of Electrical and Electronic Technology Faculty of Electrical Engineering and Communication Brno University of Technology Technická 10 616 00 Brno Czech Republic

Department of Inorganic Chemistry Faculty of Sciences Pavol Jozef Šafárik University in Košice Moyzesova 11 04154 Košice Slovak Republic

Department of Physical Chemistry Faculty of Sciences Pavol Jozef Šafárik University in Košice Moyzesova 11 04154 Košice Slovak Republic

Institute of Physics Faculty of Sciences Pavol Jozef Šafárik University in Košice Park Angelinum 9 04001 Košice Slovak Republic

Laboratory of Adsorption and Catalysis Department of Chemistry University of Antwerp Universiteitsplein 1 2610 Wilrijk Belgium

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Novel Cu(II)-based metal-organic framework STAM-1 as a sulfur host for Li-S batteries