This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 10 and group 11 metal complexes. Reductive and redox-neutral C-C bond formations catalyzed by low-valent metal complexes as well as catalytic oxidative methods are reviewed. Catalytic processes which rely on the combination of two metal complexes are also covered.
This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 8 and group 9 metal complexes. Reductive and redox-neutral coupling methods catalyzed by low-valent metal complexes as well as catalytic oxidative C-C bond formations are reviewed.
This review summarizes the current status of radical-based transition metal catalyzed reactions in organic chemistry. The underlying features of radical generation from transition metal complexes and radical reactivity in the framework of transition metal catalysis are discussed. The available arsenal to detect radicals in transition metal catalyzed transformations is presented. Available strategies to combine radical intermediates with transition metal catalysis are outlined. In the main part the currently known synthetic methodology of transition metal catalyzed reactions proceeding via radical intermediates is discussed. This part covers catalytic radical reactions involving group 4 to group 7 elements.
