Controlled photorelease of alkynoic acids and their decarboxylative deprotection for copper-catalyzed azide/alkyne cycloaddition
Status PubMed-not-MEDLINE Language English Country Great Britain, England Media print
Document type Journal Article
PubMed
29761798
DOI
10.1039/c8cc03341b
Knihovny.cz E-resources
- Publication type
- Journal Article MeSH
A controlled photorelease of alkynoic acids from the meso-methyl BODIPY photoremovable protecting group facilitates their subsequent efficient decarboxylation to give terminal alkynes for a CuI-catalyzed azide/alkyne cycloaddition. The quantum efficiencies of the photochemical step and the kinetics of the click reaction step are reported.
References provided by Crossref.org
Visible-to-NIR-Light Activated Release: From Small Molecules to Nanomaterials
