The modification of polymer materials' useful properties can be applicable in many industrial areas due to the ability to make commodity and technical plastics (plastics that offer many benefits, such as processability, by injection molding) useful in more demanding applications. In the case of injection-molded parts, one of the most suitable methods for modification appears to be high-energy irradiation, which is currently used primarily for the modification of mechanical and thermal properties. However, well-chosen doses can effectively modify the properties of the surface layer as well. The purpose of this study is to provide a complex description of high-energy radiation's (β radiation) influence on the useful properties of injection-molded parts made from common polymers. The results indicate that β radiation initiates the cross-linking process in material and leads to improved mechanical properties. Besides the cross-linking process, the material also experiences oxidation, which influences the properties of the surface layer. Based on the measured results, the main outputs of this study are appropriately designed regression models that determine the optimal dose of radiation.

• Klíčová slova
• beta radiation, cross-linking, injection molding, mechanical properties, oxidation, polymers, regression, surface properties,
• Publikační typ
• časopisecké články MeSH

The temperature ageing of high-density polyethylene (HDPE) modified by accelerated electrons was studied. Commodity plastic HDPE was used as a basic polymer material which was modified by radiation cross-linking. This polymer was used because of its excellent processability and chemical resistance. Plastic injection molding technology was used for the production of test specimens. These specimens were modified with the dose of radiation 33, 66, 99, 132, 165, and 198 kGy. The prepared specimens were tested to determine: gel content, degree of swelling, temperature stability, and changes in mechanical properties after temperature ageing. The results were determined by scanning electron microscopy (SEM) analysis on the fracture surfaces. The results of this study confirm that modification of HDPE by radiation cross-linking has a significant effect on increasing temperature stability. It has been shown that HDPE modified by radiation cross-linking can withstand temperatures exceeding the melting point of the original HDPE for a short-term.

• Klíčová slova
• high-density polyethylene, injection molding technology, mechanical properties, radiation cross-linking, temperature stability/ageing,
• Publikační typ
• časopisecké články MeSH