Today, ultramicrotome cutting is a practical tool, which is frequently applied in the preparation of thin polymeric films. One of the advantages of such a technique is the decrease in surface roughness, which enables an effective recording of further morphological changes of polymeric surfaces during their processing. In view of this, we report on ultramicrotome-cut polymers (PET, PEEK) modified by a KrF excimer laser with simultaneous decoration by AgNPs. The samples were immersed into AgNP colloid, in which they were exposed to polarized laser light. As a result, both polymers changed their surface morphology while simultaneously being decorated with AgNPs. KrF laser irradiation of the samples resulted in the formation of ripple-like structures on the surface of PET and worm-like ones in the case of PEEK. Both polymers were homogeneously covered by AgNPs. The selected area of the samples was then irradiated by a violet semiconductor laser from the confocal laser scanning microscope with direct control of the irradiated area. Various techniques, such as AFM, FEGSEM, and CLSM were used to visualize the irradiated area. After irradiation, the reverse pyramid was formed for both types of polymers. PET samples exhibited thicker transparent reverse pyramids, whereas PEEK samples showed thinner brownish ones. We believe that his technique can be effectively used for direct polymer writing or the preparation of stimuli-responsive nanoporous membranes.

• Keywords
• optomechanical manipulation, plasmon resonance, polyether etherketone, polyethylene terephthalate, silver nanoparticles, surface morphology,
• Publication type
• Journal Article MeSH

Although many noble metals are known for their antibacterial properties against the most common pathogens, such as Escherichia coli and Staphylococcus epidermidis, their effect on healthy cells can be toxic. For this reason, the choice of metals that preserve the antibacterial effect while being biocompatible with health cells is very important. This work aims to validate the effect of gold on the biocompatibility of Au/Ag nanowires, as assessed in our previous study. Polyethylene naphthalate (PEN) was treated with a KrF excimer laser to provide specific laser-induced periodic structures. Then, Au was deposited onto the modified PEN via a vacuum evaporation method. Atomic force microscopy and scanning electron microscopy revealed the dependence of the surface morphology on the incidence angle of the laser beam. A resazurin assay cytotoxicity test confirmed safety against healthy human cells and even cell proliferation was observed after 72 h of incubation. We have obtained satisfactory results, demonstrating that monometallic Au nanowires can be applied in biomedical applications and provide the biocompatibility of bimetallic Au/AgNWs.

• Keywords
• biocompatibility, gold nanowires, laser-treatment, nanocomposites, periodic structures,
• MeSH
• Anti-Bacterial Agents pharmacology   MeSH
• Escherichia coli MeSH
• Lasers MeSH
• Humans MeSH
• Naphthalenes MeSH
• Nanowires * chemistry   MeSH
• Polyethylenes MeSH
• Gold chemistry   pharmacology   MeSH
• Check Tag
• Humans MeSH
• Publication type
• Journal Article MeSH
• Names of Substances
• Anti-Bacterial Agents MeSH
• Naphthalenes MeSH
• poly(ethylene naphthalate) MeSH Browser
• Polyethylenes MeSH
• Gold MeSH

As polymeric materials are already used in many industries, the range of their applications is constantly expanding. Therefore, their preparation procedures and the resulting properties require considerable attention. In this work, we designed the surface of polyethylene naphthalate (PEN) introducing copper nanowires. The surface of PEN was transformed into coherent ripple patterns by treatment with a KrF excimer laser. Then, Cu deposition onto nanostructured surfaces by a vacuum evaporation technique was accomplished, giving rise to nanowires. The morphology of the prepared structures was investigated by atomic force microscopy and scanning electron microscopy. Energy dispersive spectroscopy and X-ray photoelectron spectroscopy revealed the distribution of Cu in the nanowires and their gradual oxidation. The optical properties of the Cu nanowires were measured by UV-Vis spectroscopy. The sessile drop method revealed the hydrophobic character of the Cu/PEN surface, which is important for further studies of biological responses. Our study suggests that a combination of laser surface texturing and vacuum evaporation can be an effective and simple method for the preparation of a Cu/polymer nanocomposite with potential exploitation in bioapplications; however, it should be borne in mind that significant post-deposition oxidation of the Cu nanowire occurs, which may open up new strategies for further biological applications.

• Keywords
• laser treatment, nanocomposites, nanostructured polymer, nanowires, periodic structures,
• Publication type
• Journal Article MeSH