Controlled/living surface-initiated ATRP of antifouling polymer brushes from gold in PBS and blood sera as a model study for polymer modifications in complex biological media
Language English Country Germany Media print
Document type Journal Article, Research Support, Non-U.S. Gov't
- MeSH
- Adsorption MeSH
- Acrylamides chemistry MeSH
- Biocompatible Materials chemical synthesis MeSH
- Blood Proteins chemistry MeSH
- Methacrylates chemistry MeSH
- Polyethylene Glycols chemistry MeSH
- Polymerization MeSH
- Buffers MeSH
- Serum MeSH
- Cattle MeSH
- Spectroscopy, Fourier Transform Infrared MeSH
- Materials Testing MeSH
- Water MeSH
- Gold chemistry MeSH
- Animals MeSH
- Check Tag
- Cattle MeSH
- Animals MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- Acrylamides MeSH
- Biocompatible Materials MeSH
- Blood Proteins MeSH
- Methacrylates MeSH
- polyethylene glycol methacrylate MeSH Browser
- Polyethylene Glycols MeSH
- Buffers MeSH
- Water MeSH
- Gold MeSH
The use of PBS, 10% FBS or 10% CS as media for SI-ATRP is reported. Controlled/living SI-ATRP of MeOEGMA in PBS is achieved leading to better control than in water. The livingness is confirmed by chain extension with MeOEGMA or carboxybetaine acrylamide. This technique is successfully adopted for the polymerization of MeOEGMA in 10% FBS or CS as models for complex biological media with reasonable control of the brush growth. All prepared brushes show excellent antifouling properties.
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