Influence of Processing Techniques on Microstructure and Mechanical Properties of a Biodegradable Mg-3Zn-2Ca Alloy
Status PubMed-not-MEDLINE Language English Country Switzerland Media electronic
Document type Journal Article
PubMed
28774000
PubMed Central
PMC5457187
DOI
10.3390/ma9110880
PII: ma9110880
Knihovny.cz E-resources
- Keywords
- ECAP processing, Mg-Zn-Ca, biodegradable magnesium alloy, mechanical properties, microstructure, squeeze casting,
- Publication type
- Journal Article MeSH
New Mg-3Zn-2Ca magnesium alloy was prepared using different processing techniques: gravity casting as well as squeeze casting in liquid and semisolid states. Materials were further thermally treated; thermal treatment of the gravity cast alloy was additionally combined with the equal channel angular pressing (ECAP). Alloy processed by the squeeze casting in liquid as well as in semisolid state exhibit improved plasticity; the ECAP processing positively influenced both the tensile and compressive characteristics of the alloy. Applied heat treatment influenced the distribution and chemical composition of present intermetallic phases. Influence of particular processing techniques, heat treatment, and intermetallic phase distribution is thoroughly discussed in relation to mechanical behavior of presented alloys.
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Advesian M.M., Baker H. ASM Specialty Handbook: Magnesium and Magnesium Alloys. ASM International; Materials Park, OH, USA: 1999.
Witte F., Fischer J., Nellesen J., Crostack H.-A., Kaese V., Pisch A., Beckmann F., Windhagen H. In vitro and in vivo corrosion measurements of magnesium alloys. Biomaterials. 2006;27:1013–1018. doi: 10.1016/j.biomaterials.2005.07.037. PubMed DOI
Staiger M.P., Pietak A.M., Huadmai J., Dias G. Magnesium and its alloys as orthopedic biomaterials: A review. Biomaterials. 2006;27:1728–1734. doi: 10.1016/j.biomaterials.2005.10.003. PubMed DOI
Zhang B., Hou Y., Wang X., Wang Y., Geng L. Mechanical properties, degradation performance and cytotoxicity of Mg-Zn-Ca biomedical alloys with different compositions. Mater. Sci. Eng. C. 2011;31:1667–1673. doi: 10.1016/j.msec.2011.07.015. DOI
Gupta M., Sharon N.M.L. Magnesium, Magnesium Alloys, and Magnesium Composites. John Wiley & Sons; Hoboken, NJ, USA: 2011.
Du H., Wei Z., Liu X., Zhang E. Effects of Zn on the microstructure, mechanical property and bio-corrosion property of Mg-3Ca alloys for biomedical application. Mater. Chem. Phys. 2011;125:568–575. doi: 10.1016/j.matchemphys.2010.10.015. DOI
Zhang S., Zhang X., Zhao C., Li J., Song Y., Xie C., Tao H., Zhang Y., He Y., Jiang Y., et al. Research on an Mg-Zn alloy as a degradable biomaterial. Acta Biomater. 2010;6:626–640. doi: 10.1016/j.actbio.2009.06.028. PubMed DOI
Baltzer N., Copponnex T. Precious Metals for Biomedical Applications. Elsevier Science; Cambridge, UK: 2014.
Raman R.K.S., Harandi S.E. Understanding Corrosion-Assisted Cracking of Magnesium Alloys for Bioimplant Applications. In: Singh A., Solanki K., Manuel M.V., Neelameggham N.R., editors. Magnesium Technology 2016. John Wiley & Sons; Hoboken, NJ, USA: 2016.
Beck A. Magnesium und Seine Legierungen. Springer; Berlin/Heidelberg, Germany: 1939.
Ben-Hamu G., Eliezer D., Shin K.S. The role of Si and Ca on new wrought Mg-Zn-Mn based alloy. Mater. Sci. Eng. A. 2007;447:35–43. doi: 10.1016/j.msea.2006.10.059. DOI
Jardim P.M., Solorzano G., Sande J.B.V. Second phase formation in melt-spun Mg-Ca-Zn alloys. Mater. Sci. Eng. A. 2004;381:196–205. doi: 10.1016/j.msea.2004.04.043. DOI
Yin D.-S., Zhang E.-L., Zeng S.-Y. Effect of Zn on mechanical property and corrosion property of extruded Mg-Zn-Mn alloy. Trans. Nonferr. Met. Soc. 2008;18:763–768. doi: 10.1016/S1003-6326(08)60131-4. DOI
Xu L., Yu G., Zhang E., Pan F., Yang K. In vivo corrosion behavior of Mg-Mn-Zn alloy for bone implant application. J. Biomed. Mater. Res. A. 2007;83:703–711. doi: 10.1002/jbm.a.31273. PubMed DOI
Geng L., Zhang B.P., Li A.B., Dong C.C. Microstructure and mechanical properties of Mg-4.0Zn-0.5Ca alloy. Mater. Lett. 2009;63:557–559. doi: 10.1016/j.matlet.2008.11.044. DOI
Ortega Y., Monge M.A., Pareja R. The precipitation process in Mg-Ca-(Zn) alloys investigated by positron annihilation spectroscopy. J. Alloys Compd. 2008;463:62–66. doi: 10.1016/j.jallcom.2007.09.044. DOI
Sun Y., Zhang B., Wang Y., Geng L., Jiao X. Preparation and characterization of a new biomedical Mg-Zn-Ca alloy. Mater. Des. 2012;34:58–64. doi: 10.1016/j.matdes.2011.07.058. DOI
Oh J.C., Ohkubo T., Mukai T., Hono K. TEM and 3DAP characterization of an age-hardened Mg-Ca-Zn alloy. Scr. Mater. 2005;53:675–679. doi: 10.1016/j.scriptamat.2005.05.030. DOI
Wan Y., Xiong G., Luo H., He F., Huang Y., Zhou X. Preparation and characterization of a new biomedical magnesium–calcium alloy. Mater. Des. 2008;29:2034–2037. doi: 10.1016/j.matdes.2008.04.017. DOI
Li Z., Gu X., Lou S., Zheng Y. The development of binary Mg-Ca alloys for use as biodegradable materials within bone. Biomaterials. 2008;29:1329–1344. doi: 10.1016/j.biomaterials.2007.12.021. PubMed DOI
Larionova T.V., Park W.-W., You B.-S. A ternary phase observed in rapidly solidified Mg-Ca-Zn alloys. Scr. Mater. 2001;45:7–12. doi: 10.1016/S1359-6462(01)00982-4. DOI
Sustek V., Cadek J., Spigarelli S. Creep behavior at high stresses of a Mg-Zn-Ca-Ce-La alloy processed by rapid solidification. Scr. Mater. 1996;35:449–454. doi: 10.1016/1359-6462(96)00141-8. DOI
You B.S., Park W.W., Chung I.S. The effect of calcium additions on the oxidation behavior in magnesium alloys. Scr. Mater. 2000;42:1089–1094. doi: 10.1016/S1359-6462(00)00344-4. DOI
Gao X., Zhu S.M., Muddle B.C., Nie J.F. Precipitation-hardened Mg-Ca-Zn alloys with superior creep resistance. Scr. Mater. 2005;53:1321–1326. doi: 10.1016/j.scriptamat.2005.08.035. DOI
Gu X.N., Zhou W.R., Zheng Y.F., Cheng Y., Wei S.C., Zhong S.P., Xi T.F., Chen L.J. Corrosion fatigue behaviors of two biomedical Mg alloys—AZ91D and WE43—In simulated body fluid. Acta Biomater. 2010;6:4605–4613. doi: 10.1016/j.actbio.2010.07.026. PubMed DOI
Ghomashchi M.R., Vikhrov A. Squeeze casting: An overview. J. Mater. Process. Technol. 2000;101:1–9. doi: 10.1016/S0924-0136(99)00291-5. DOI
Kleiner S., Beffort O., Wahlen A., Uggowitzer P.J. Microstructure and mechanical properties of squeeze cast and semi-solid cast Mg-Al alloys. J. Light Met. 2002;2:277–280. doi: 10.1016/S1471-5317(03)00012-9. DOI
Wagener W., Hartmann D., Lehnert F., Scholz K. Mechanical Properties of Magnesium Alloys Processed by Semi-Solid Casting. In: Kainer K.U., editor. Magnesium Alloys and their Applications. Wiley-VCH Verlag GmbH & Co.; Weinheim, Germany: 2006. pp. 291–295.
Metallic Materials—Tensile Testing—Part 1: Method of Test at Room Temperature. International Organization for Standardization; Geneva, Switzerland: 2016. ISO 6892-1:2016.
Von Mises R. Mechanik der plastischen Formänderung von Kristallen. Z. Angew. Math. Mech. 1928;8:161–185. doi: 10.1002/zamm.19280080302. DOI
Mendelson S. Dislocations in HCP Metals. J. Appl. Phys. 1970;41:1893–1910. doi: 10.1063/1.1659139. DOI
Trojanová Z., Lukáč P. Physical aspects of plastic deformation in Mg-Al alloys with Sr and Ca. Int. J. Mater. Res. 2009;100:270–276. doi: 10.3139/146.110054. DOI
Labusch R. Statistische Theorien der Mischkristallhärtung. (Statistical theories of solid solution hardening) Acta Metall. 1972;20:917–927. doi: 10.1016/0001-6160(72)90085-5. DOI
Wang Y.N., Huang J.C. The role of twinning and untwinning in yielding behavior in hot-extruded Mg-Al-Zn alloy. Acta Mater. 2007;55:897–905. doi: 10.1016/j.actamat.2006.09.010. DOI
Klimanek P., Pötzsch A. Microstructure evolution under compressive plastic deformation of magnesium at different temperatures and strain rates. Mater. Sci. Eng. A. 2002;324:145–150. doi: 10.1016/S0921-5093(01)01297-7. DOI
Trojanová Z., Cáceres C.H., Lukáč P., Čížek L. Serrated flow in AZ91 magnesium alloy in tension and compression. Kovove Mater. 2008;46:243–248.
Cáceres C.H., Rodriguez A.H. Acoustic emission and deformation bands in Al-2.5%Mg and Cu-30%Zn. Acta Metall. Mater. 1987;35:2851–2864. doi: 10.1016/0001-6160(87)90284-7. DOI
Grain Size-Related Strengthening and Softening of a Precompressed and Heat-Treated Mg-Zn-Ca Alloy