Superhydrophobicity, UV protection and oil/water separation properties of fly ash/Trimethoxy(octadecyl)silane coated cotton fabrics

. 2018 Dec 15 ; 202 () : 571-580. [epub] 20180912

Status PubMed-not-MEDLINE Jazyk angličtina Země Anglie, Velká Británie Médium print-electronic

Typ dokumentu časopisecké články

Perzistentní odkaz   https://www.medvik.cz/link/pmid30287038
Odkazy

PubMed 30287038
DOI 10.1016/j.carbpol.2018.08.145
PII: S0144-8617(18)31056-7
Knihovny.cz E-zdroje

The presented study proposed simple and low-cost approach for improvement in UV protection and superhydrophobic properties of cotton fabrics by coating of mechanically activated fly ash particles. The maximum UV blocking was observed for 3 wt% fly ash, where UV transmittance decreased from 14.19% of untreated fabric to 0.11% of coated fabric. After subsequent treatment of Trimethoxy(octadecyl)silane (OTMS) on fly ash coated fabrics, the water contact angle was increased to 143°, 147° and 153° for fly ash concentration of 1, 2 and 3 wt% respectively. From Cassie-Baxter theories, the unwetted fraction of air pockets were estimated to be 43%, 55% and 67% respectively for 1, 2 and 3 wt% of fly ash particles. Furthermore, the coated fabrics showed great potentials for separation of floating oil layer, underwater oil droplet or oil/water mixture. The separation efficiency of 98%, 96%, 97% and 95% was obtained for selected model oils toluene, n-hexane, chloroform and petro ether, respectively.

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