In the past few years, aqueous zinc-metal batteries (ZMBs) have gained much attention and can be regarded as a potential alternative to lithium-metal batteries owing to their high safety, nature of abundance, and environmental sustainability. However, several challenges persist, including dendrite formation, corrosion, and unwanted side reactions, before ZMBs can be fully utilized in practical applications. To circumvent these issues, anode free zinc-metal batteries (AFZMBs) have emerged as a next-generation energy storage system. This review provides a comprehensive analysis of recent developments in AFZMBs, including their working mechanisms, advantages over conventional ZMBs, and the challenges for practical implementation. It also highlights the key strategies, including current collector modification, electrolyte engineering, and 3D printing techniques to enhance zinc deposition uniformity and cycling stability. The review also explores how 3D printing technology can revolutionize the design of advanced current collectors and zinc-rich cathodes, optimizing material utilization and enhancing battery performance. Finally, with a future perspective of AFZMBs is concluded, highlighting the need for further research to address existing bottlenecks and fully unlock their potential for next-generation energy storage.

• Keywords
• 3D printing, advantages and challenges, anode free zinc‐metal batteries, current collector, electrolyte optimization, strategies,
• Publication type
• Journal Article MeSH
• Review MeSH

Additive manufacturing technology, referred as 3D printing technology, is a growing research field with broad applications from nanosensors fabrication to 3D printing of buildings. Nowadays, the world is dealing with a pandemic and requires the use of simple sensing systems. Here, the strengths of fast screening by a lab-on-a-chip device through electrochemical detection using 3D printing technology for SARS-CoV-2 sensing are combined. This system comprises a PDMS microfluidic channel integrated with an electrochemical cell fully 3D-printed by a 3D printing pen (3D-PP). The 3D-PP genosensor is modified with an ssDNA probe that targeted the N gene sequence of SARS-CoV-2. The sensing mechanism relies on the electro-oxidation of adenines present in ssDNA when in contact with SARS-CoV-2 RNA. The hybridization between ssDNA and target RNA takes a place and ssDNA is desorbed from the genosensor surface, causing a decrease of the sensor signal. The developed SARS-CoV-2/3D-PP genosensor shows high sensitivity and fast response.

• Keywords
• additive manufacturing, electroanalysis, lab on chip, nucleic acid,
• Publication type
• Journal Article MeSH

3D printing technology has brought light in the fight against the COVID-19 global pandemic event through the decentralized and on-demand manufacture of different personal protective equipment and medical devices. Nonetheless, since this technology is still in an early stage, the use of 3D-printed electronic devices for antigen test developments is almost an unexplored field. Herein, a robust and general bottom-up biofunctionalization approach via surface engineering is reported aiming at providing the bases for the fabrication of the first 3D-printed COVID-19 immunosensor prototype with electronic readout. The 3D-printed COVID-19 immunosensor was constructed by covalently anchoring the COVID-19 recombinant protein on a 3D-printed graphene-based nanocomposite electrode surface. The electrical readout relies on impedimetrically monitoring changes at the electrode/electrolyte interface after interacting with the monoclonal COVID-19 antibody via competitive assay, fact that hinders the redox conversion of a benchmark redox marker. Overall, the developed 3D-printed system exhibits promising electroanalytical capabilities in both buffered and human serum samples, displaying an excellent linear response with a detection limit at trace levels (0.5 ± 0.1 μg·mL-1). Such achievements demonstrate advantage of light-of-speed distribution of 3D printing datafiles with localized point-of-care low-cost printing and bioelectronic devices to help contain the spread of emerging infectious diseases such as COVID-19. This technology is applicable to any post-COVID-19 SARS diseases.

• Keywords
• 3D-printed electrodes, Antigen test, Electrochemical detection, SARS-CoV-2, Surface engineering,
• Publication type
• Journal Article MeSH

3D-printing technology provided numerous contributions to the health sector during the recent Coronavirus disease 2019 (COVID-19) pandemic. Several of the 3D-printed medical devices like personal protection equipment (PPE), ventilators, specimen collectors, safety accessories, and isolation wards/ chambers were printed in a short time as demands for these were rising significantly. The review discusses some of these contributions of 3D-printing that helped to protect several lives during this health emergency. By enlisting some of the significant benefits of using the 3D-printing technique during an emergency over other conventional methods, this review claims that the former opens enormous possibilities in times of serious shortage of supply and exceeding demands. This review acknowledges the collaborative approaches adopted by individuals, entrepreneurs, academicians, and companies that helped in forming a global network for delivering 3D-printed medical/non-medical components, when other supply chains were disrupted. The collaboration of the 3D-printing technology with the global health community unfolds new and significant opportunities in the future.

• Keywords
• 3D‐printing, COVID‐19, medical urgency, pandemic, personal protective equipment, swabs, ventilators,
• Publication type
• Journal Article MeSH

The combination of computer assisted design and 3D printing has recently enabled fast and inexpensive manufacture of customized 'reactionware' for broad range of electrochemical applications. In this work bi-material fused deposition modeling 3D printing is utilized to construct an integrated platform based on a polyamide electrochemical cell and electrodes manufactured from a polylactic acid-carbon nanotube conductive composite. The cell contains separated compartments for the reference and counter electrode and enables reactants to be introduced and inspected under oxygen-free conditions. The developed platform was employed in a study investigating the electrochemical oxidation of aqueous hydrazine coupled to its bulk reaction with carbon dioxide. The analysis of cyclic voltammograms obtained in reaction mixtures with systematically varied composition confirmed that the reaction between hydrazine and carbon dioxide follows 1/1 stoichiometry and the corresponding equilibrium constant amounts to (2.8 ± 0.6) × 103. Experimental characteristics were verified by results of numerical simulations based on the finite-element-method.

• Keywords
• 3D printing, Carbon dioxide, Electrochemical measurements, Hydrazine, Numerical simulations,
• Publication type
• Journal Article MeSH