Sufficient mixing is crucial for the proper performance of anaerobic digestion (AD), creating a homogeneous distribution of soluble substrates, biomass, pH, and temperature. The opaqueness of the sludge and mode of operation make it challenging to study AD mixing experimentally. Therefore, hydrodynamics modelling employing computational fluid dynamics (CFD) is often used to investigate this mixing. However, CFD models mostly do not include biochemical reactions and, hence, ignore the effect of diffusion-induced transport on AD heterogeneity. The novelty of this work is the partial integration of Anaerobic Digestion Model no. 1 (ADM1) into the CFD model. The aim is to better understand the effect of advection-diffusion transport on the homogenization of soluble substrates and biomass. Furthermore, AD homogeneity analysis in terms of concentration distribution is proposed rather than the traditional velocity distributions. The computed results indicate that including diffusion-induced transport affects the homogeneity of AD.
- MeSH
- anaerobióza MeSH
- bioreaktory MeSH
- difuze MeSH
- hydrodynamika * MeSH
- odpadní vody MeSH
- teoretické modely * MeSH
- Publikační typ
- časopisecké články MeSH
Stormwater sediments of various sizes and densities are recognised as one of the most important stormwater quality parameters that can be conventionally controlled by settling in detention ponds. The bottom grid structure (BGS) is an innovative concept proposed in this study to enhance removal of stormwater sediments entering ponds and reduce sediment resuspension. This concept was studied in a hydraulic scale model with the objective of elucidating the effects of the BGS geometry on stormwater sediment trapping. Towards this end, the BGS cell size and depth, and the cell cross-wall angle were varied for a range of flow rates, and the sediment trapping efficiency was measured in the model. The main value of the observed sediment trapping efficiencies, in the range from 13 to 55%, was a comparative assessment of various BGS designs. In general, larger cells (footprint 10 × 10 cm) were more effective than the smaller cells (5 × 5 cm), the cell depth exerted small influence on sediment trapping, and the cells with inclined cross-walls proved more effective in sediment trapping than the vertical cross-walls. However, the BGS with inclined cross-walls would be harder to maintain. Future studies should address an optimal cell design and testing in an actual stormwater pond.
- MeSH
- geologické sedimenty * MeSH
- rybníky * MeSH
- zátoky MeSH
- Publikační typ
- časopisecké články MeSH
The foul odour of cheese-production wastewater is a common problem in areas surrounding dairy wastewater treatment plants. For successful odour management, a better understanding of the key odorants and how to handle them during wastewater treatment is needed. This paper documents the results of using gas chromatography-mass spectrometry coupled with olfactometry (GC-MS/O) to analyze odours emanating from a possibly overloaded treatment plant in Czechia. Using a DB5 capillary column, 20 compounds were detected and identified, nonanal (FDgeomean 152) and octen-3-ol (FDgeomean 2048) having the most pungent odours.
Urban hydrology was created in order to improve methods of managing the runoff of precipitation in towns and protect them from flooding while also protecting public health and environment. The essence of a future solution consists in finding an acceptable compromise of an alternative solution for draining rainwater from a territory. The content of this work is a study focused on resolving the percolation of water from surface runoff and the confrontation between a field test, laboratory analysis, and numerical analysis. By confronting and subsequently proposing conditions for percolation, documents will be created for making urban drainage better and more efficient. The reason for the origin of the subject work follows from the insufficient information on infiltration systems in Slovak technical standards and, likewise, the lack of support for the percolation of water from surface runoff. This work points out the approaches, principles, and fundamentals of a proposal for percolation. The aim of the work is distribution of scientific knowledge in the field of research and solutions for the percolation of water from surface runoff, with emphasis placed on the retention capacity of the selected territory and the intensity of precipitation. A geological study (orientational, detailed or supplementary) must always be conducted with any decision on rainwater percolation in a certain locality. Its range is dependent on the difficulty and type of construction. The preliminary study of areal condition should be focused on detailed engineering-geological and hydrological information. After this work, it is concluded that the percolation of rainwater in urban areas with suitable hydrogeological condition is an effective rainwater management technology as well as protection to congestion of sewer systems.
- MeSH
- déšť * MeSH
- hydrologie MeSH
- odpad tekutý - odstraňování MeSH
- pohyb vody MeSH
- Publikační typ
- časopisecké články MeSH
- Geografické názvy
- velkoměsta MeSH
Flow data represent crucial input for reliable diagnostics of sewer functions and identification of potential problems such as unwanted inflow and infiltration. Flow estimates from pumping stations, which are an integral part of most separate sewer systems, might help in this regard. A robust model and an associated optimization procedure is proposed for estimating inflow to a pumping station using only registered water levels in the pump sump and power consumption. The model was successfully tested on one month of data from a single upstream station. The model is suitable for identification of pump capacity and volume thresholds for switching the pump on and off. These are parameters which are required for flow estimation during periods with high inflows or during periods with flow conditions triggering pump switching on and off at frequencies close to the temporal resolution of monitored data. The model is, however, sensitive within the transition states between emptying and filling to observation errors in volume and on inflow/outflow variability.
Over the past few decades, reverse osmosis (RO) has been the dominant technology employed in zero liquid discharge (ZLD) systems for industrial wastewater treatment (WWT). However, RO is limited to a maximum operating salinity of about 75 g kg-1. Electrodialysis (ED) is a potentially attractive option as it can achieve much higher concentrations, thereby reducing the capacity and energy demand of the subsequent evaporation step. Feed-and-bleed experiments were undertaken on a laboratory-scale ED stack using a series of model solutions based on the most common inorganic salts with the aim of determining maximum achievable concentrations. The maximum salt concentration achievable via ED ranged between 104.2 and 267.6 g kg-1, with levels predominantly limited by water transport. In addition, a straightforward review of how ED incorporation can affect ZLD process economics is presented. The operational cost of an ED-based ZLD system for processing RO retentate was almost 20% lower than comparable processes employing high-efficiency RO and disc tubular RO. As the ED-based ZLD system appears economically preferable, and as maximum achievable concentrations greatly exceeded RO operating limits, it would appear to be a promising approach for bridging the gap between RO and evaporation, and may even eliminate the evaporation step altogether.
Identifying the fouling degree of a membrane bioreactor (MBR) provides guidance on the determination of suitable membrane cleaning methods. There is still a lack of knowledge on the effects of powdered activated carbon (PAC) refresh ratio on the MBR fouling mechanism. Major fouling mechanisms of an MBR with constant flow rate at different PAC replenishment ratios were investigated by individual and combined mechanistic fouling models. The root mean square errors were employed to assess the prediction accuracy of the used fouling models. The combined models showed better prediction. The cake-complete model provided far better fits of the transmembrane pressure data, and provided good fits of other individual model predictions regardless of the PAC refreshment ratio. Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy confirmed that the cake layer clogging was the main fouling mechanism followed by complete blockage and standard plugging. The cake-complete model may be used to predict the fouling mechanisms in PAC/MBR systems.
Postaeration, where digested sludge is introduced into aerobic conditions, is a technology that could improve the quality of sludge and sludge liquor in many ways. Although it is a fairly simple process, only few data about the effect of postaeration have been published. In this study, batch experiments have been performed first, indicating that postaeration affects the total ammonia nitrogen (TAN) and sludge dewaterability. In the removal of TAN, both stripping and biological oxidation can play an important role depending on specific condition. Then the postaeration was investigated in a semicontinuous batch reactor. In addition, the effect of postaeration on the concentration of selected micropollutants such as pharmaceuticals, EOX and AOX was studied. The hydraulic retention time (HRT) of 8, 6, 4 and 2 days and different aeration intensities were tested. The TAN removal efficiency achieved was about 40-60%, sludge dewaterability expressed by sludge cake total solids (TS) concentration after dewatering improved relatively by 5-30%. In addition, TS degradation is also taking place and therefore the reduction of the amount of final sludge to be disposed could be even higher. The biggest changes in observed parameters were recorded at the longest HRT.
- MeSH
- amoniak MeSH
- bioreaktory MeSH
- dusík MeSH
- odpad tekutý - odstraňování * MeSH
- odpadní vody * MeSH
- Publikační typ
- časopisecké články MeSH
Adsorption characteristics of high-silica zeolites (HSZSM-5) for two selected sulfonamide antibiotics (SAs) (sulfamethoxazole and sulfadiazine) were investigated. The SAs were almost completely (>90%) removed from the water by HSZSM-5. Adsorption followed second-order kinetics with liquid-film diffusion as the dominant mechanism. SA adsorption capacity on high-silica zeolites was examined in terms of pH, temperature, and the presence of natural organic matter (NOM). HSZSM-5 had better adsorption performance in acidic conditions, and the apparent distribution coefficient indicated that SA0 species were the major contribution to the overall adsorption at pH of 2-10. Adsorption of SAs on HSZSM-5 was a spontaneous and exothermic physisorption process. SA removal by HSZSM-5 was a mixed mechanism through ion-exchange and hydrophobic interaction. HSZSM-5 has potential application prospects in removing SAs from wastewater.
This work focuses on the removal of ammonia nitrogen pollution from wastewaters in a two-stage laboratory model based on a combination of the nitritation and anammox processes with the biomass immobilized in a polyvinyl alcohol (PVA) matrix. Owing to the immobilization approach inside the PVA pellets, the bacterial activity remained nearly unchanged on an abrupt change in the environmental conditions. The nitritation kinetics were significantly dependent on the dissolved oxygen concentration. The critical dissolved oxygen concentration at which the nitritation process using the immobilized bacterial culture stops is 0.6 mg/L. The volumetric rate of nitrogen removal by the anammox bacteria was 158 mg/(L·d). The technology presented is well-suited for removing high ammonia nitrogen concentrations (≥300 mg/L).
