Biowaste
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Biowaste valorisation into high-value compounds is one of the main challenges of green chemistry, as chemicals produced from biological sources are identified as key substances in the development of a low-carbon and circular bioeconomy in connection with the transition from fossil to renewable feedstocks. The review summarizes the production of high-value products such as glucose-based chemicals, phenolic compounds and volatile-fatty acids prepared from biomass waste. Biowaste pretreatment methods such as milling, filtration and extraction followed by current non-catalytic methods such as microwave or ultrasound extraction and catalytic methods for the production value-added compounds in the presence of various catalyst types in conventional, nano or enzyme form are listed with a focus on value-added chemicals applied in the food, cosmetic and pharmaceutical industries. The economic feasibility, technical aspects and concept of the biorefinery are briefly mentioned, emphasizing the necessity of life cycle assessment for each bioproduct and technological process. Finally, it provides a future perspective and makes recommendations for potential research strategies, recognizing the importance of utilizing biomass waste for the production of useful compounds as an attractive and environmentally friendly approach whose development should be encouraged. The utilization of biowaste for high-value chemicals production shows high potential, however, there are still many challenges to be resolved throughout the entire production chain, reflecting technological, economic, ecological, sociological and long-term issues.
- Klíčová slova
- Added-value chemicals, Biowaste conversion, Biowaste valorisation, Catalysis, High-value compounds, Polysaccharide, Volatile fatty acids,
- MeSH
- biomasa MeSH
- farmaceutický průmysl MeSH
- kosmetické přípravky * chemie MeSH
- potravinářský průmysl MeSH
- průmyslový odpad analýza MeSH
- Publikační typ
- časopisecké články MeSH
- přehledy MeSH
- Názvy látek
- kosmetické přípravky * MeSH
- průmyslový odpad MeSH
Today, sustainable and natural resources including biowastes have been considered attractive starting materials for the fabrication of biocompatible and biodegradable carbon dots (CDs) due to the benefits of availability, low cost, biorenewability, and environmentally benign attributes. These carbonaceous nanomaterials have been widely explored in the field of sensing/imaging, optoelectronics, photocatalysis, drug/gene delivery, tissue engineering, regenerative medicine, and cancer theranostics. Designing multifunctional biowaste-derived CDs with a high efficacy-to-toxicity ratio for sustained and targeted drug delivery, along with imaging potentials, opens a new window of opportunity toward theranostic applications. However, crucial challenges regarding the absorption/emission wavelength, up-conversion emission/multiphoton fluorescence mechanisms, and phosphorescence of these CDs still need to be addressed to attain the maximum functionality and efficacy. Future studies ought to focus on optimizing the synthesis techniques/conditions, evaluating the influence of nucleation/growth process on structures/properties, controlling their morphology/size, and finding the photoluminescence mechanisms. Reproducibility of synthesis techniques is another critically important factor that needs to be addressed in the future. Herein, the recent developments related to the biowaste-derived CDs with respect to their biomedical applications are deliberated, focusing on important challenges and future perspectives.
- Klíčová slova
- biocompatibility, biomedical applications, biowaste-derived carbon dots, green chemistry, sustainability, valorization,
- MeSH
- diagnostické zobrazování MeSH
- kvantové tečky * MeSH
- lékové transportní systémy MeSH
- reprodukovatelnost výsledků MeSH
- uhlík * MeSH
- Publikační typ
- časopisecké články MeSH
- přehledy MeSH
- Názvy látek
- uhlík * MeSH
As part of coming targets to transition to a sustainable society and actively set a circular economy, one of the EU objectives is to decrease the amount of municipal solid waste and initiate the separation of its organic fraction, i.e., biowaste. Consequently, the question of how to best manage biowaste at the municipal level is of high importance, and previous research has shown the strong influence of local factors on the most sustainable treatment option. Life Cycle Assessment is a valuable tool for comparison of waste management impacts and was used to assess environmental impacts of the current biowaste management in Prague and give insight for improvements. Different scenarios were created regarding EU and Czech biowaste targets for separated collection. Results show the significant influence of the source of energy that is substituted. Consequently, in the current situation of an energy mix highly based on fossil fuels, incineration is the most sustainable option in most impact categories. However, community composting was found to have a better potential to reduce ecotoxicity and resource use of minerals and metals. Furthermore, it could supply a significant proportion of the minerals need of the region while increasing the autonomy of the Czech Republic regarding mineral fertilisers. To meet targets of EU directives for separated collection of biowaste, a combination of anaerobic digestion, to avoid use of fossil fuels, and composting, to increase circular economy, is most likely the best option. The outputs of this project would be of great significance for municipalities.
- Klíčová slova
- Biowaste, Environmental assessment, Life cycle assessment, Organic fraction of municipal solid waste, Waste management,
- MeSH
- nakládání s odpady * metody MeSH
- odpadky - odstraňování * metody MeSH
- stadia vývoje MeSH
- tuhý odpad analýza MeSH
- zvířata MeSH
- Check Tag
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- Geografické názvy
- Česká republika MeSH
- Názvy látek
- tuhý odpad MeSH
Nowadays, dealing with organic waste (or biowaste) remains a global phenomenon. Especially developing countries worldwide generate more than 50 percent organicwaste. In the European Union (EU) with a share of 34%, biowaste is a dominantfraction of the municipal waste (EEA, 2020). Therefore, separate collection at source and environmentally sound treatment of biowaste are of key importance. An intensive optimisation of biowaste separate collection is needed to balance demands of municipal representatives and households' needs. Based on the mixed-method approach we developed a MCDA model complemented by expert-based weighting assessment and combined with the GIS localisation tools aimed at the optimisation of biowaste container locations that reflects various spatial conditions, preconditions for the localisation of containers and its cost intensity. We concluded that changing the density of containers, distance between the address point and container, and selecting container locations that respect the habits of households and demands of the collection technology significantly affect the total and collection costs. We confirmed that the decreases in the total costs were not significant for maximum walking distances of over 95 m, and would approach zero for distances of over 230 m. When the maximum walking distance exceeds 268 m, 40% of all inhabitants would not participate in the system as it would be inconvenient for them. A recycling campaign is needed to increase their willingness to participate in the system. We provided arguments for decision-makers how to balance convenience of the biowaste separation system and collection costs by proper localisation of biowaste containers.
- Klíčová slova
- Biowaste, Costs, Geographic Information System, Localization of containers, Separate collection,
- MeSH
- charakteristiky rodiny MeSH
- geografické informační systémy MeSH
- odpadky - odstraňování * MeSH
- recyklace MeSH
- Publikační typ
- časopisecké články MeSH
Compost leachate (CL) is often treated as sewage. Limited studies have characterised the use of CL for agriculture application due to the variation of nutrient range, potential pollutants and need for pretreatment before use. This paper reviewed the characteristics of CL in terms of its nutrients and physical characteristics from three types of biowastes, i.e. the organic portion of municipal solid waste (OP-MSW), animal manure and green waste. The nutrient range characterised are used to develop the dilution rate of the CL as fertigation water for three types of vegetables. The dilution rate of CL developed is based on the fertigation standards set by the Food and Agriculture Organization of the United Nations and Malaysia Standards. The results show that all CL contain high organic content and micronutrients, which exceeded the upper limits. For the fertigation of vegetables using the CL, based on the requirement of COD and micronutrients (Fe, Mn, Zn, Cu, Pb, Ni, Cd, Cr) of the vegetables, the CL from green waste required the lowest dilution rate (8-45 fold), followed by animal waste (33-65 fold) and the OP-MSW (193-1770 fold). The novel dilution range developed is vital to balance the essential nutrients in the CL while avoiding phototoxicity on plant and soil pollution. The dilution strategy developed is essential to support the conversion of CL as an organic liquid fertiliser for agricultural application.
- Klíčová slova
- Biowaste, Compost leachate, Dilution rate, Fertigation, Nutrient range,
- MeSH
- kompostování * MeSH
- látky znečišťující půdu * analýza MeSH
- půda MeSH
- těžké kovy * analýza MeSH
- tuhý odpad MeSH
- zelenina MeSH
- zvířata MeSH
- Check Tag
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- Geografické názvy
- Malajsie MeSH
- Názvy látek
- látky znečišťující půdu * MeSH
- půda MeSH
- těžké kovy * MeSH
- tuhý odpad MeSH
Laser ablation in liquid (LAL), one of the promising pathways to produce nanoparticles, is used herein for the modification of the abundant biowaste, calcium lignosulfonate (CLS), adorning it with palladium nanoparticles (Pd NPs). The ensuing Pd/CLS nanocomposite, fabricated via a simple stirring method, is deployed for hydrogen storage and environmental cleanup studies; a hydrogen storage capacity of about 5.8 C g-1 confirmed that Pd NPs serve as active sites for the adsorption of hydrogen. Additionally, the novel, sustainable, and reusable nanocomposite also exhibits superior catalytic activity toward the reduction of hexavalent chromium [Cr(VI)], 4-nitrophenol (4-NP), and methylene blue (MB) in an aqueous solution in a short time; the synthesized nanocatalyst could be reused for at least eight successive runs.
- Publikační typ
- časopisecké články MeSH
The temperature of matured compost is an indicator of feedstock quality and also a good feedback informing about the suitability of an applied technological procedure. Two independent experiments using the technology of windrow composting at open area were conducted with the final goal to evaluate the effect of compost pile covering (in comparison with uncovered piles) on the course of composting process - behaviour of temperature over time and oxygen content. Two types of sheets were used - Top Tex permeable sheet and impermeable polyethylene sheet. The experiment I (summer months) aimed at comparison of efficiency between the Top Tex sheet cover and the uncovered compost piles, while experiment II (autumn months) compared treatments using the Top Tex sheet and polyethylene sheet by contrast. Within the experiment I the composts consisted of cattle slurry and fresh grass matter at a ratio of 1:1, in case of experiment II consisted of pig/cattle manure, fresh grass matter and chipped material at a ratio of about 1:2:1. The obtained data showed no significant differences among the cover treatments according to ANOVA. The only exception was oxygen content in pile 4 (experiment II) under Top Tex sheet, where a markedly higher oxygen content than under polyethylene sheet was measured during the whole composting period. It was the only case where statistical analysis proved a significant difference; the p-value was 0.0002.
The implementation of circular economy (CE) strategies has facilitated a comprehensive approach to waste management (WM) in university campuses. Composting food waste (FW) and biomass can mitigate negative environmental impacts and be part of a closed-loop economy. The compost can be used as a fertilizer, thereby closing the waste cycle. Implementing nudging strategies to promote effective waste segregation can help the campus move closer towards achieving neutrality and sustainability goals. The research was conducted at the Warsaw University of Life Sciences - WULS (SGGW). The University Campus is located in the south of Warsaw (Poland) and covers an area of 70 ha with 49 buildings. The SGGW campus generates selectively collected (glass, paper, plastic and metals, and biowaste) and mixed waste. Data were collected through a year-long report from the university administration. For the survey, waste data from 2019 to 2022 were obtained. The CE efficiency indicators of CE were measured. The indicators of CE efficiency for compost (Ic,ce) and plastic (Ipb,ce) showed Ic,ce at 21.05 %, which means that 1/5th of the waste generated on the campus can be introduced into the CE paradigm through composting, and the resulting value Ipb,ce of 19.96 % indicates that this amount can be reintroduced into the CE paradigm through its reuse. The results of the seasonality study showed that there were no statistically significant differences in the generated biowaste between the separated periods of the year, and the Pearson correlation coefficient (r = 0.068) provided additional confirmation. The weak correlation between the amount of biowaste generated and the average for each year (r = 0.110) also indicates a stable biowaste generation system that does not require a reduction or increase in the efficiency of waste processing, such as composting. By implementing CE strategies, university campuses can improve WM practices and achieve sustainability goals.
- Klíčová slova
- Biowaste, Circular economy, Higher Education Institutions, Sustainable development, Waste management,
- MeSH
- lidé MeSH
- nakládání s odpady * MeSH
- odpadky - odstraňování * MeSH
- plastické hmoty MeSH
- potraviny MeSH
- univerzity MeSH
- Check Tag
- lidé MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- plastické hmoty MeSH
Large-scale vermicomposting under outdoor conditions may differ from small-scale procedures in the laboratory. The present study evaluated changes in selected properties of a large-scale vertical-flow windrow vermicomposting system with continuous feeding with household biowaste. The windrow profile was divided into five layers of differing thickness and age after more than 12 months of vermicomposting. The top layer (0-30 cm, age <3 months) was characterised by partially decomposed organic matter with a high pH value and an elevated carbon/nitrogen (C/N) ratio. The earthworm biomass was 15 g kg-1 with a population density of 125 earthworms per kilogram predominantly found in clusters. The greatest amount of fungi (3.5 µg g-1 dw) and bacteria (62 µg g-1 dw) (expressed as phospholipid fatty acid analysis) was found in this layer. Thus, the top layer could be used for an additional cycle of windrow vermicomposting and for the preparation of aqueous extracts to protect plants against diseases. The lower layers (graduated by 30 cm and by 3 months of age) were mature as reflected by the low content of ammonia nitrogen, ratio of ammonia to nitrate nitrogen and dissolved organic carbon, and high ion-exchange capacity and its ratio to carbon. These layers were characterised by elevated values for electrical conductivity, total content of nutrients, available magnesium content, and a relatively large bacterial/fungal ratio. On the basis of the observed properties, the bottom layers were predetermined as effective fertilisers.
- Klíčová slova
- Large-scale windrow vermicomposting, biowaste, continuous feeding, earthworms, micro-organisms,
- MeSH
- biodegradace MeSH
- kompostování metody MeSH
- odpadky - odstraňování metody MeSH
- Oligochaeta * MeSH
- půda MeSH
- zvířata MeSH
- Check Tag
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- půda MeSH
Vermicomposting is a process of degradation of biowaste which involves complex interactions between earthworms and microorganisms. This process lacks a thermophilic stage and thus, the possible presence of pathogens poses a potential health hazard. To assess the contribution of earthworms during the selective reduction of various pathogens, apple pomace substrate was artificially inoculated with Escherichia coli, Salmonella spp., thermotolerant coliform bacteria, and Enterococci. The artificial bacterial load did not influence the weight, reproduction, or intestinal enzymatic activity of the earthworms, but it caused reversible histological changes to the epithelial layer and chloragogen tissue of their intestines. The reduction of pathogenic Enterococci and E. coli from the substrate was accelerated by earthworms (63-fold, 77-fold, and 840-fold for Enterococci and 6-fold, 36-fold, and 7-fold for E. coli inoculated substrates after 2, 4, and 6 weeks, respectively). Moreover, the rapid elimination of Salmonella spp. was supported by the upregulated expression of two pattern recognition receptors which bind lipopolysaccharide, coelomic cytolytic factor, and lipopolysaccharide-binding protein. Further, the microbiomes of the intestine and the composting substrate differed significantly. Graphical abstract.
- Klíčová slova
- Biowaste, Earthworm, Eisenia, Immunity, Microbiome, Pathogen, Pattern recognition receptor, Vermicompost,
- MeSH
- Escherichia coli MeSH
- kompostování metody MeSH
- Oligochaeta mikrobiologie fyziologie MeSH
- půdní mikrobiologie * MeSH
- střevní mikroflóra * MeSH
- zvířata MeSH
- Check Tag
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- hodnotící studie MeSH
