Isotopes Dotaz Zobrazit nápovědu
- Klíčová slova
- RADIOISOTOPES *,
- MeSH
- izotopy * MeSH
- radionuklidy * MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- izotopy * MeSH
- radionuklidy * MeSH
Diverse isotopes such as 2H, 3He, 10Be, 11C and 14C occur in nuclear reactions in ion beam radiotherapy, in cosmic ray shielding, or are intentionally accelerated in dating techniques. However, only a few studies have specifically addressed the biological effects of diverse isotopes and were limited to energies of several MeV/u. A database of simulations with the PARTRAC biophysical tool is presented for H, He, Li, Be, B and C isotopes at energies from 0.5 GeV/u down to stopping. The doses deposited to a cell nucleus and also the yields per unit dose of single- and double-strand breaks and their clusters induced in cellular DNA are predicted to vary among diverse isotopes of the same element at energies < 1 MeV/u, especially for isotopes of H and He. The results may affect the risk estimates for astronauts in deep space missions or the models of biological effectiveness of ion beams and indicate that radiation protection in 14C or 10Be dating techniques may be based on knowledge gathered with 12C or 9Be.
- Klíčová slova
- DNA damage, Monte Carlo simulations, analytical functions, ionizing radiation, isotopes, track structure,
- MeSH
- DNA MeSH
- ionty MeSH
- izotopy * MeSH
- metoda Monte Carlo MeSH
- poškození DNA * MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- DNA MeSH
- ionty MeSH
- izotopy * MeSH
Lead (Pb) isotopic analyses proved to be a very efficient tool for tracing the sources of local and global Pb pollution. This review presents an overview of literature published on the use of Pb isotopic analyses of different environmental matrices (atmospheric aerosols, lichens, tree rings, peat deposits, lake, stream, marine sediments, soils, etc.). In order to gain more insight, the isotopic compositions of major sources of Pb in the environment as determined by several authors are described in detail. These include, above all, the former use of leaded gasoline, coal combustion, industrial activities (e.g., metallurgy) and waste incineration. Furthermore, this review summarises analytical techniques (especially ICP-MS) used for the determination of Pb isotopes in environmental samples.
Peatland degradation is tightly connected to hydrological changes and microbial metabolism. To better understand these metabolism processes, more information is needed on how microbial communities and substrate cycling are affected by changing hydrological regimes. These activities should be imprinted in stable isotope bulk values (δ 15N, δ 13C) due to specific isotopic fractionation by different microbial communities, their metabolic pathways and nutrient sources. We hypothesize that stable isotope values and microbial abundance are correlated and act as indicators of different hydrological regimes. We sampled an East-West transect across European fens in 14 areas and conducted a stable isotope (δ 13C, δ 15N) and membrane fatty acid (mFA) analysis. Within each area an undrained, drained and rewetted site was selected. Rewetted sites were separated based on when rewetting occurred. We found differences in the upper layers of all sites in microbial-derived mFAs and stable isotope values corresponding to hydrological regimes. The highest and lowest quantities of microbial-derived mFAs were measured in undrained and drained sites, respectively. Fungal-derived mFAs were especially lower in drained sites. Simultaneously, δ15N stable isotope values were highest in drained sites. In addition, stable isotope values and microbial-derived mFAs showed distinct depth trends. In undrained sites stable isotopes values slightly increased with depth. In drained sites, δ15N values decreased downwards, whereas δ13C values increased. Overall microbial-derived mFAs decreased with depth. These patterns presumably result from anoxic conditions and high peat recalcitrance in the deeper layers. In sites with short time of rewetting, the microbial-derived mFAs and stable isotope values were similar to values of drained sites, while with increasing rewetting time values shifted to those of undrained sites. We conclude that biomarkers indicate that stable isotope values reflect specific microbial metabolic processes, which differ with hydrological regimes, and thus could indicate both drainage and rewetting in fens.
- Klíčová slova
- European fens, Membrane fatty acids, Peatland degradation, Rewetting, Stable isotopes,
- MeSH
- biologické markery MeSH
- hydrologie * MeSH
- izotopy dusíku analýza MeSH
- izotopy uhlíku MeSH
- mikrobiota * MeSH
- půda MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- biologické markery MeSH
- izotopy dusíku MeSH
- izotopy uhlíku MeSH
- půda MeSH
As an iron is the main structural component of nuclear power plants as well as future fusion power plants, the validation of neutron incident data libraries of iron is a must. Presented paper fits into ongoing validation activities and presents measuring neutron leakage spectra in the 0.1-1.0MeV region from iron sphere of 100cm in diameter by hydrogen proportional detectors. The experimental result is compared with ENDF/B-VII.1, JEFF-3.2 and CIELO nuclear data libraries. No library reasonably well describes whole region under study. Furthermore, elastic and inelastic XS sensitivity analysis for all iron isotopes was carried out. 54Fe isotope elastic XS influence is comparable with 56Fe XS influence up to 0.8MeV. 57Fe isotope elastic XS is significant in the region of 0.14-0.15MeV. Additionally, there are large differences among libraries in both elastic and inelastic XS for 57Fe. Furthermore, it was found that 58Fe isotope XS has negligible influence on the results. As a neutron source, 252Cf with initial emission rate of 9.53E8 n/s was used in this experiment.
- Klíčová slova
- (252)Cf, Cross section, Natural iron isotopes, Natural iron sphere,
- Publikační typ
- časopisecké články MeSH
Present and future climatic trends are expected to markedly alter water fluxes and stores in the hydrologic cycle. In addition, water demand continues to grow due to increased human use and a growing population. Sustainably managing water resources requires a thorough understanding of water storage and flow in natural, agricultural, and urban ecosystems. Measurements of stable isotopes of water (hydrogen and oxygen) in the water cycle (atmosphere, soils, plants, surface water, and groundwater) can provide information on the transport pathways, sourcing, dynamics, ages, and storage pools of water that is difficult to obtain with other techniques. However, the potential of these techniques for practical questions has not been fully exploited yet. Here, we outline the benefits and limitations of potential applications of stable isotope methods useful to water managers, farmers, and other stakeholders. We also describe several case studies demonstrating how stable isotopes of water can support water management decision-making. Finally, we propose a workflow that guides users through a sequence of decisions required to apply stable isotope methods to examples of water management issues. We call for ongoing dialogue and a stronger connection between water management stakeholders and water stable isotope practitioners to identify the most pressing issues and develop best-practice guidelines to apply these techniques.
- Klíčová slova
- Agricultural management, Climate change, Forest management, Stable isotopes of water, Stakeholders, Water resources management,
- MeSH
- ekosystém * MeSH
- izotopy analýza MeSH
- lesy * MeSH
- ochrana vodních zdrojů metody MeSH
- podzemní voda chemie MeSH
- vodní zdroje MeSH
- zemědělství * metody MeSH
- Publikační typ
- časopisecké články MeSH
- přehledy MeSH
- Názvy látek
- izotopy MeSH
Here, for the first time, we report the concentrations and isotopic data of Ag in a variety of ore and metallurgical samples and forest soils that have been polluted due to Ag-Pb smelter emissions. Similar to the Ag concentrations, we identified a large range of δ109Ag values (from -0.8 to +2.4‰), a ∼3‰ spread, within the primary and secondary materials (i.e., galena, fly ash, slag and matte). This phenomenon, however, is evidently unrelated to Ag isotopic fractionation during the smelting process, but it reflects the starting 109Ag/107Ag signal in ore mineral and/or the specific type of ore genesis. The two studied soil profiles differed in Ag isotopic composition, but on the other hand, they consistently showed significantly lighter Ag (≤+0.8‰) of metallurgical origin in the upper horizons compared to the bottom horizons and bedrocks, with low Ag amounts depleted of 107Ag (≤+2.9‰). This isotopic pattern can be attributed to a ternary mixing relationship involving two major anthropogenic Ag components and a minor contribution from geogenic Ag. Accordingly, we did not observe any post-depositional isotopic fractionation in our soils, since Ag was geochemically stable and it was not subjected to leaching. In summary, the Ag isotopes have a potential to trace variations in anthropogenic phases, to monitor specific geochemical processes, and are clearly applicable as anthropogenic Ag source and Ag load proxies.
During the past decade, parasites have been considered important components of their ecosystems since they can modify food-web structures and functioning. One constraint to the inclusion of parasites in food-web models is the scarcity of available information on their feeding habits and host-parasite relationships. The stable isotope approach is suggested as a useful methodology to determine the trophic position and feeding habits of parasites. However, the isotopic approach is limited by the lack of information on the isotopic discrimination (ID) values of parasites, which is pivotal to avoiding the biased interpretation of isotopic results. In the present study we aimed to provide the first ID values of δ(15)N and δ(13)C between the gyrocotylidean tapeworm Gyrocotyle urna and its definitive host, the holocephalan Chimaera monstrosa. We also test the effect of host body size (body length and body mass) and sex of the host on the ID values. Finally, we illustrate how the trophic relationships of the fish host C. monstrosa and the tapeworm G. urna could vary relative to ID values. Similar to other studies with parasites, the ID values of the parasite-host system were negative for both isotopic values of N (Δδ(15)N = - 3.33 ± 0.63‰) and C (Δδ(13)C = - 1.32 ± 0.65‰), independent of the sex and size of the host. By comparing the specific ID obtained here with ID from other studies, we illustrate the importance of using specific ID in parasite-host systems to avoid potential errors in the interpretation of the results when surrogate values from similar systems or organisms are used.
- MeSH
- Cestoda chemie fyziologie MeSH
- Chordata parazitologie MeSH
- interakce hostitele a parazita MeSH
- izotopové značení MeSH
- izotopy dusíku analýza MeSH
- izotopy uhlíku analýza MeSH
- parazitologie metody MeSH
- zvířata MeSH
- Check Tag
- mužské pohlaví MeSH
- ženské pohlaví MeSH
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- izotopy dusíku MeSH
- izotopy uhlíku MeSH
The grains of three barley varieties were milled and sieved to obtain respective milling fractions with a content of beta-glucans (b-G) from 1.4 to 10.7%. The enriched fraction obtained by the extraction and precipitation contained 24.7% of b-G. The differences between the ratio of stable C carbon isotopes were established. Milling fractions with coarse particles had more beta-glucans and a more negative ratio of δ13C isotope in comparison to the respective intact barley grain. However, the enriched fraction had a less negative isotope ratio. So, it is not expected that the deviation from the stable isotope ratio of grain in milling fractions is the result of the content of b-G, but it depends on other barley grain constituents. In different parts of barley grain, there are substances with different stable isotope ratios, and by milling and sieving, they are assorted to the same milling fraction with most of the b-G. The method for determining the ratio of a stable carbon isotope in diverse barley grain fractions, applied in this investigation, is potentially opening the possibility for an additional method of screening the concentration of bioactive constituents in barley grain.
- Klíčová slova
- barley, beta-glucans, milling, nutrition, stable isotopes, starch,
- MeSH
- beta-glukany * MeSH
- izotopy uhlíku MeSH
- ječmen (rod) * MeSH
- jedlá semena MeSH
- uhlík MeSH
- Publikační typ
- časopisecké články MeSH
- Názvy látek
- beta-glukany * MeSH
- izotopy uhlíku MeSH
- uhlík MeSH
Stable isotope measurements are increasingly being used to gain insights into the nutritional ecology of many wildlife species and their role in ecosystem structure and function. Such studies require estimations of trophic discrimination factors (i.e. differences in the isotopic ratio between the consumer and its diet). Although trophic discrimination factors are tissue- and species-specific, researchers often rely on generalized, and fixed trophic discrimination factors that have not been experimentally derived. In this experimental study, captive wild boar (Sus scrofa) were fed a controlled diet of corn (Zea mays), a popular and increasingly dominant food source for wild boar in the Czech Republic and elsewhere in Europe, and trophic discrimination factors for stable carbon (Δ13C) and nitrogen (Δ15N) isotopes were determined from hair samples. The mean Δ13C and Δ15N in wild boar hair were -2.3‰ and +3.5‰, respectively. Also, in order to facilitate future derivations of isotopic measurements along wild boar hair, we calculated the average hair growth rate to be 1.1 mm d(-1). Our results serve as a baseline for interpreting isotopic patterns of free-ranging wild boar in current European agricultural landscapes. However, future research is needed in order to provide a broader understanding of the processes underlying the variation in trophic discrimination factors of carbon and nitrogen across of variety of diet types.
- MeSH
- dieta veterinární MeSH
- izotopy dusíku analýza MeSH
- izotopy uhlíku analýza MeSH
- kukuřice setá chemie MeSH
- nutriční stav MeSH
- potravní řetězec MeSH
- Sus scrofa růst a vývoj MeSH
- vlasy, chlupy chemie růst a vývoj MeSH
- zvířata MeSH
- Check Tag
- mužské pohlaví MeSH
- zvířata MeSH
- Publikační typ
- časopisecké články MeSH
- práce podpořená grantem MeSH
- Názvy látek
- izotopy dusíku MeSH
- izotopy uhlíku MeSH
