The very early stages of alkaline activation of slag control its rheology and setting, but also affect its hydration, which occurs later. Simultaneously, these parameters are dictated by the nature and dose of the alkaline activator. Therefore, we investigated and compared the changes in slag particles (SEM, BET, laser diffraction), as well as in the pore solution composition (ICP-OES), pH, and conductivity, of alkali-activated slag (AAS) pastes containing the three most common sodium activators (waterglass, hydroxide, and carbonate) and water during the first 24 h of its activation. To ensure the best possible comparability of the pastes, a fairly nontraditional mixture design was adopted, based on the same concentration of Na+ (4 mol/dm3) and the same volume fraction of slag in the paste (0.50). The results were correlated with the pastes' hydration kinetics (isothermal calorimetry), structural build-up (oscillatory rheology), and setting times (Vicat). Great differences were observed in most of these properties, in the formation of hydration products, and in the composition of the pore solution for each activator. The results emphasize the role of the anionic groups in the activators and of the pH, which help predict the sample's behavior based on its calorimetric curve, and offer data for further comparisons and for the modelling of AAS hydration for specific activators.

• Klíčová slova
• BET surface, activator, alkali-activated slag, hydration kinetics, hydration products, morphology, pore solution, scanning electron microscopy, setting,
• Publikační typ
• časopisecké články MeSH

This study investigates the relationships between the hydration kinetics of waterglass-activated slag and the development of its physical-mechanical properties, as well as its color change. To modify the calorimetric response of alkali-activated slag, hexylene glycol was selected from various alcohols for in-depth experiments. In presence of hexylene glycol, the formation of initial reaction products was restricted to the slag surface, which drastically slowed down the further consumption of dissolved species and slag dissolution and consequently delayed the bulk hydration of the waterglass-activated slag by several days. This allowed to show that the corresponding calorimetric peak is directly related to the rapid evolution of the microstructure and physical-mechanical parameters and to the onset of a blue/green color change recorded as a time-lapse video. Workability loss was correlated with the first half of the second calorimetric peak, while the most rapid increase in strengths and autogenous shrinkage was related to the third calorimetric peak. Ultrasonic pulse velocity increased considerably during both the second and third calorimetric peak. Despite the modified morphology of the initial reaction products, the prolonged induction period, and the slightly reduced degree of hydration induced by hexylene glycol, the overall mechanism of alkaline activation remained unchanged in the long-term perspective. It was hypothesized that the main issue of the use of organic admixtures in alkali-activated systems is the destabilizing effect of these admixtures on soluble silicates introduced into the system with an activator.

• Klíčová slova
• alkali-activated slag, calorimetry, color change, microstructure, organic admixture, pore solution, retardation, setting, shrinkage,
• Publikační typ
• časopisecké články MeSH

The electrical properties of concrete are gaining their importance for the application in building construction. In this study, graphite powder was added to alkali-activated slag mortar as an electrically conductive filler in order to enhance the mortar's conductive properties. The amount of graphite ranged from 1% to 30% of the slag mass. The effect of the graphite powder on the resistivity, capacitance, mechanical properties, and microstructure of the composite was investigated. Selected mixtures were then used for the testing of self-sensing properties under compressive loading. The results show that the addition of an amount of graphite equal to up to 10% of the slag mass improved the electrical properties of the alkali-activated slag. Higher amounts of filler did not provide any further improvement in electrical properties at lower AC frequencies but caused a strong deterioration in mechanical properties. The best self-sensing properties were achieved for the mixture with 10 wt% of graphite, but only at low compressive stresses of up to 6 MPa.

• Klíčová slova
• alkali-activated slag, compressive strength, electrical resistivity, graphite, microstructure, self-sensing,
• Publikační typ
• časopisecké články MeSH

In recent years, the utilization of different non-traditional cements and composites has been increasing. Alkali-activated cementitious materials, especially those based on the alkali activation of blast furnace slag, have considerable potential for utilization in the building industry. However, alkali-slag cements exhibit very rapid setting times, which are too short in some circumstances, and these materials cannot be used for some applications. Therefore, it is necessary to find a suitable retarding admixture. It was shown that the sodium phosphate additive has a strong effect on the heat evolution during alkali activation and effectively retards the hydration reaction of alkali-activated blast furnace slag. The aim of the work is the suggestion of a reaction mechanism of retardation mainly based on Raman and X‑ray photoelectron spectroscopy.

• Klíčová slova
• alkali activated cement, granulated blast furnace slag, retardation,
• Publikační typ
• časopisecké články MeSH

In this study, four ecotoxicological tests on Vibrio fischeri bacteria, Sinapis alba L. (white mustard), Daphnia magna S. (daphnia's) and earthworms were performed for three types of aqueous slag (ladle, blast furnace and converter) leachates with two-grain sizes (<4 mm, <10 mm). Concentrations of toxic elements and concentrations of Cr(VI), Ca, Na, Al, and other ions were determined. The raw slags were analyzed using X-ray fluorescence spectroscopy (XRFS), and major substances were determined by X-ray powder diffraction (XRD). The aqueous slag leachates passed ecotoxicological tests and met the required criteria, showing no toxicity to Vibrio fischeri and complying with white mustard test criteria. According to the results of the ecotoxicity tests with daphnia, the blast furnace slag samples were not ecotoxic, while two other slag samples were found to be entirely compliant. Characterization of the slags showed that the effect of element/ion leachability and slag grain size is essential. Biplot principal component analysis (PCA) showed that grain size does not significantly affect the separation of individuals on the plane. A positive correlation on toxicity was found with pH, conductivity, calcium content, dissolved content, salinity and fluoride concentration, whereas a negative correlation was found with magnesium concentration, dissolved organic carbon and potassium concentration. The effective concentration at 50% inhibition (EC50) value for Vibrio fischeri correlated with the first dimension of bivariate assessment. In summary, it was found that the investigated slags can be effectively reused as they comply with regulations and do not endanger the environment.

• Klíčová slova
• Blast furnace slag, Converter slag, Ecotoxicity, Ladle slag, Leachability, PCA analysis,
• MeSH
• Aliivibrio fischeri * účinky léků   MeSH
• chemické látky znečišťující vodu toxicita   analýza   chemie   MeSH
• Daphnia * účinky léků   MeSH
• ekotoxikologie * MeSH
• hořčice rodu Sinapis účinky léků   chemie   MeSH
• Oligochaeta účinky léků   MeSH
• testy toxicity MeSH
• zvířata MeSH
• Check Tag
• zvířata MeSH
• Publikační typ
• časopisecké články MeSH
• Názvy látek
• chemické látky znečišťující vodu MeSH

The rationalization of material flows, together with the utilization of waste raw materials for the production of alternative binders, became a very attractive topic during the last decades. However, the majority of designed materials can be used as a replacement for low-performance products. In this work, the waste materials (brick powder and blast furnace slag) are valorized through geopolymerization to design high-performance material as an alternative to high-performance concrete. Designed mixtures activated by sodium silicate and waste-originated alkali solution are characterized by the meaning of the chemical and mineralogical composition, evolution of hydration heat, and mechanical strength test. To contribute to the understanding of the environmental consequences and potential benefits, the carbon footprint and embodied energy analysis are provided. Obtained results highlight the potential of end-of-life bricks for the design of high-performance composites if mixed together with more reactive precursors. Here, even values over 60 MPa in compressive strength can be achieved with the dominant share of low-amorphous brick powder. The higher crystalline portion of brick powder may lead to the reduction of drying shrinkage and preservation of flexural strength to a greater extent compared to used slag. Performed environmental analysis confirmed the CO2 emission savings; however, the embodied energy analysis revealed a huge impact of using alkaline activators.

• Klíčová slova
• alkali activation, blast furnace slag, brick powder, environmental footprint, geopolymer, mechanical strength,
• Publikační typ
• časopisecké články MeSH

Ferrous slag produced by a historic smelter is washed from a slagheap and transported by a creek through a cave system. Slag filling cave spaces, abrasion of cave walls / calcite speleothems, and contamination of the aquatic environment with heavy metals and other toxic components are concerns. We characterize the slag in its deposition site, map its transport through the cave system, characterize the effect of slag transport, and evaluate the risks to both cave and aqueous environments. The study was based on chemical and phase analysis supported laboratory experiments and geochemical modeling. The slag in the slagheap was dominated by amorphous glass phase (66 to 99 wt%) with mean composition of 49.8 ± 2.8 wt% SiO2, 29.9 ± 1.6 wt% CaO, 13.4 ± 1.2 wt% Al2O3, 2.7 ± 0.3 wt% K2O, and 1.2 ± 0.1 wt% MgO. Minerals such as melilite, plagioclase, anorthite, and wollastonite / pseudowollastonite with lower amounts of quartz, cristobalite, and calcite were detected. Slag enriches the cave environment with Se, As, W, Y, U, Be, Cs, Sc, Cd, Hf, Ba, Th, Cr, Zr, Zn, and V. However, only Zr, V, Co, and As exceed the specified limits for soils (US EPA and EU limits). The dissolution lifetime of a 1 mm3 volume of slag was estimated to be 27,000 years, whereas the mean residence time of the slag in the cave is much shorter, defined by a flood frequency of ca. 47 years. Consequently, the extent of slag weathering and contamination of cave environment by slag weathering products is small under given conditions. However, slag enriched in U and Th can increase radon production as a result of alpha decay. The slag has an abrasive effect on surrounding rocks and disintegrated slag can contaminate calcite speleothems.

• Klíčová slova
• Environmental risk, Experimental abrasion, Ferrous slag, Pollutant release, Rudice Sink – Býčí skála Cave System, Slag transport/weathering,
• MeSH
• kadmium analýza   MeSH
• křemen analýza   MeSH
• minerály analýza   MeSH
• oxid hořečnatý analýza   MeSH
• oxid křemičitý analýza   MeSH
• půda MeSH
• radon * analýza   MeSH
• silikáty MeSH
• sloučeniny vápníku MeSH
• těžké kovy * analýza   MeSH
• uhličitan vápenatý analýza   MeSH
• Publikační typ
• časopisecké články MeSH
• Geografické názvy
• Česká republika MeSH
• Názvy látek
• calcium silicate MeSH Prohlížeč
• kadmium MeSH
• křemen MeSH
• minerály MeSH
• oxid hořečnatý MeSH
• oxid křemičitý MeSH
• půda MeSH
• radon * MeSH
• silikáty MeSH
• sloučeniny vápníku MeSH
• těžké kovy * MeSH
• uhličitan vápenatý MeSH

Significant drying shrinkage is one of the main limitations for the wider utilization of alkali-activated slag (AAS). Few previous works revealed that it is possible to reduce AAS drying shrinkage by the use of shrinkage-reducing admixtures (SRAs). However, these studies were mainly focused on SRA based on polypropylene glycol, while as it is shown in this paper, the behavior of SRA based on 2-methyl-2,4-pentanediol can be significantly different. While 0.25% and 0.50% had only a minor effect on the AAS properties, 1.0% of this SRA reduced the drying shrinkage of waterglass-activated slag mortar by more than 80%, but it greatly reduced early strengths simultaneously. This feature was further studied by isothermal calorimetry, mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). Calorimetric experiments showed that 1% of SRA modified the second peak of the pre-induction period and delayed the maximum of the main hydration peak by several days, which corresponds well with observed strength development as well as with the MIP and SEM results. These observations proved the certain incompatibility of SRA with the studied AAS system, because the drying shrinkage reduction was induced by the strong retardation of hydration, resulting in a coarsening of the pore structure rather than the proper function of the SRA.

• Klíčová slova
• alkali activated slag, hydration, microstructure, retardation, shrinkage, shrinkage reducing admixture,
• Publikační typ
• časopisecké články MeSH

The former Pb-Zn mining town of Kabwe in central Zambia is ranked amongst the worst polluted areas both in Africa and in the world. The fine dust particles from the ISF and Waelz slags deposited in Kabwe represent a health risk for the local population. Here, we combined a detailed multi-method mineralogical investigation with oral bioaccessibility testing in simulated gastric fluid (SGF; 0.4 M glycine, pH 1.5, L/S ratio of 100, 1 h, 37 °C) to evaluate the risk related to the incidental dust ingestion. The slag dust fractions contain up to 2610 mg/kg V, 6.3 wt% Pb and 19 wt% Zn. The metals are mainly bound in a slag glass and secondary phases, which formed during the slag weathering or were windblown from nearby tailing stockpiles (carbonates, Fe and Mn oxides, phosphates, vanadates). The bioaccessible fractions (BAFs) are rather high for all the main contaminants, with the BAF values generally higher for the ISF slags than for the Waelz slags: Pb (24-96%), V (21-100%) and Zn (54-81%). The results clearly indicate the potential risks related to the incidental slag dust ingestion. Even when a conservative value of the dust daily intake (100 mg/day) is considered, the daily contaminant intake significantly exceeds the tolerable daily intake limits, especially for Pb ≫ V > Zn. At higher ingestion rates, other minor contaminants (As, Cd) also become a health risk, especially for children. The slag heaps in Kabwe should be fenced to prevent local people entering and should be covered to limit the dust dispersion.

• Klíčová slova
• Bioaccessibility, Kabwe, Metal(loid)s, Mineralogy, Pb–Zn slag Dusts,
• MeSH
• dítě MeSH
• hornictví MeSH
• kovy analýza   MeSH
• látky znečišťující životní prostředí MeSH
• lidé MeSH
• monitorování životního prostředí MeSH
• prach analýza   MeSH
• průmyslový odpad * MeSH
• velkoměsta MeSH
• vystavení vlivu životního prostředí * MeSH
• Check Tag
• dítě MeSH
• lidé MeSH
• Publikační typ
• časopisecké články MeSH
• Geografické názvy
• velkoměsta MeSH
• Zambie MeSH
• Názvy látek
• kovy MeSH
• látky znečišťující životní prostředí MeSH
• prach MeSH
• průmyslový odpad * MeSH

Waste slag which is created during precious metal smelting contains high levels of potentially toxic elements (PTE) which can be mobilised from unconfined deposits into the local environment. This paper examines the extractability of selected PTE (Pb, Zn, Cd, Mn) from slag samples by synthetic solutions designed to replicate those in the environment. Extracting agents were used to replicate potential leaching scenarios which are analogous to natural chemical weathering. Slag was submersed in a rainwater simulation solution (RSS), weak citric acid solution (representing rhizosphere secretions) and control solutions (deionised water) for a one month period with solution analyses made at intervals of 1, 24, 168 and 720 h. In 1 mM citric acid, dissolution of Cd and Zn showed little change with time, although for Zn the initial dissolution was considerable. Lead in citric acid was characterized by overall poor extractability. Mn solubility increased until an equilibrium state occurred within 24 h. The solubility of studied metals in citric acid can be characterized by a short time to equilibrium. RSS proved to be an effective solvent that, unlike citric acid solution, extracted increasing concentrations of Cd, Mn and Zn with time. Solubility of Pb in RSS was again very low. When taken as a proportion of a single 2 M HNO3 extraction which was applied to slag samples, Cd was the element most readily leached into RSS and control samples. In both studied solvents, slag heterogeneity is prominent in the case of Cd and Zn solubility. Contact time with solvent appears to be an important variable for the release of PTE from slag into solution. The purpose of this study was to provide insight into the environmental chemical dissolution of PTE from slag, which causes their enrichment in surrounding soils and surface waters.

• Klíčová slova
• Citric acid, Extraction experiment, Potentially toxic elements, Rainwater simulation solution, Smelter slag,
• MeSH
• déšť chemie   MeSH
• hutnictví MeSH
• kyselina citronová chemie   MeSH
• látky znečišťující půdu analýza   chemie   MeSH
• monitorování životního prostředí MeSH
• rozpouštědla chemie   MeSH
• spektrofotometrie atomová MeSH
• stříbro analýza   chemie   MeSH
• těžké kovy analýza   chemie   MeSH
• znečištění životního prostředí analýza   MeSH
• Publikační typ
• časopisecké články MeSH
• práce podpořená grantem MeSH
• Geografické názvy
• Česká republika MeSH
• Názvy látek
• kyselina citronová MeSH
• látky znečišťující půdu MeSH
• rozpouštědla MeSH
• stříbro MeSH
• těžké kovy MeSH