The widespread use of polymers in the high-performance engineering applications brings challenges in the field of liquid lubrication in order to separate the rubbing surfaces by the coherent fluid-film thickness relative to not only the inelastic material response of the polymers. The determination of the mechanical properties by the nanoindentation and the dynamic mechanical analysis represents the key methodology to identify the viscoelastic behavior with respect to the intense frequency and temperature dependance exhibited by polymers. The fluid-film thickness was examined by the optical chromatic interferometry on the rotational tribometer in the ball-on-disc configuration. Based on the experiments performed, first, the complex modulus and the damping factor for the PMMA polymer describing the frequency and temperature dependence were obtained. Afterwards, the central as well as minimum fluid-film thickness were investigated. The results revealed the operation of the compliant circular contact in the transition region very close to the boundary between the Piezoviscous-elastic and Isoviscous-elastic modes of the elastohydrodynamic lubrication regime, and a significant deviation of the fluid-film thickness from the prediction models for both modes in dependence on the inlet temperature.
- Keywords
- compliant contact, elastohydrodynamic lubrication, fluid-film thickness, optical chromatic interferometry, transition region, viscoelastic behavior,
- Publication type
- Journal Article MeSH
In this work, advanced polymer nanocomposites comprising of polyvinyl alcohol (PVA) and nanodiamonds (NDs) were developed using a single-step solution-casting method. The properties of the prepared PVA/NDs nanocomposites were investigated using Raman spectroscopy, small- and wide-angle X-ray scattering (SAXS/WAXS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA). It was revealed that the tensile strength improved dramatically with increasing ND content in the PVA matrix, suggesting a strong interaction between the NDs and the PVA. SEM, TEM, and SAXS showed that NDs were present in the form of agglomerates with an average size of ~60 nm with primary particles of diameter ~5 nm. These results showed that NDs could act as a good nanofiller for PVA in terms of improving its stability and mechanical properties.
- Keywords
- mechanical properties, morphology, nanocomposite, nanodiamond, poly (vinyl alcohol),
- Publication type
- Journal Article MeSH
Load response of viscoelastic-plastic materials depends on the load magnitude and history, and can be described by rheological models consisting of springs and dashpots. The parameters in these models can be obtained by instrumented indentation. Time-dependent properties are determined best from the time course of indenter displacement under constant load, but one must consider also the initial loading history. For characterization of instantaneous elastic and plastic response, fast loading and unloading are necessary. The paper summarizes the formulae for indentation into elastic-plastic and viscoelastic-plastic materials, and proposes a procedure for testing and data evaluation. Its application is illustrated on the indentation of human enamel.
- MeSH
- Biomechanical Phenomena MeSH
- Humans MeSH
- Nanotechnology instrumentation methods MeSH
- Elasticity * MeSH
- Hardness Tests instrumentation methods MeSH
- Viscosity MeSH
- Weight-Bearing MeSH
- Dental Enamel MeSH
- Check Tag
- Humans MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
The majority of investigations consider the deformation response of hydrogels, fully controlled by the deformation behavior of their polymer network, neglecting the contribution caused by the presence of water. Here, we use molecular dynamics simulation in an attempt to include the effect of physically bound water via polymer chain solvation on the viscoelastic response of hydrogels. Our model allows us to control the solvation of chains as an independent variable. The solvation of the chain is independent of other factors, mainly the effect (pH) which interferes significantly in experiments. The solvation of hydrophilic chains was controlled by setting a partial charge on the chains and quantified by the Bjerrum length (BL). The BL was calculated from the partial electric charge of the solvent and macromolecular network. When the BL is short, the repulsive Van der Waals interactions are predominant in the vicinity of macromolecules and solvation is not observed. For a long BL, the water molecules in the solvation zone of network are in the same range as attractive intermolecular forces and the solvation occurs. The model also allows the consideration of molecules of water attached to two chains simultaneously, forming a temporary bridging. By elucidating the relations between solvation of the network and structural changes during the network deformation, one may predict the viscoelastic properties of hydrogels knowing the molecular structure of its polymer chains.
- Keywords
- deformation, hydrogel, molecular dynamics, solvation, water,
- Publication type
- Journal Article MeSH
OBJECTIVE: To evaluate and compare the viscoelastic properties of dentine and resin-based dental materials by bulk compressive test and the Burgers model. MATERIALS AND METHODS: Sound dentine, three resin composites as well as a resin-based cement were prepared into cylindrical specimens (n = 8). A bulk compressive creep test was applied with a constant load of 300 N (23.9 MPa) for 2 h, followed by another 2 h recovery. The maximum strain, creep stain, percentage of recovery and permanent set was measured using a linear variable displacement transducer. The viscoelastic properties were characterized via the Burgers model, and the instantaneous elastic, viscous as well as elastic delayed deformation were separated from the total strain. Data were analysed via ANOVA (or Welch's Test) and Tukey (or Games-Howell Test) with a significance level of 0.05. RESULTS: Sound dentine presented the lowest maximum strain, creep strain, permanent set and the highest percentage of recovery, followed by 3 resin composites with comparable parameters, while the cement showed a significantly higher maximum strain, permanent set and lower percentage of recovery (p < 0.001). The Burgers model presented acceptable fits for characterization viscoelastic processes of both dentine and resin-based dental materials. Viscous and elastic delayed strain of dentine was significantly lower than those for tested materials (p < 0.001) with the highest instantaneous elastic strain percentage. Similar viscous and delayed strain was found among the 4 resin-based materials (p > 0.05). SIGNIFICANCE: Sound dentine exhibited superior creep stability compared to resin-based dental materials. The viscous deformation in sound dentine could be ignored when loading parallel to dentine tubules.
- Keywords
- Burgers model, Creep, Dentine, Resin composite, Viscoelastic,
- MeSH
- Dental Stress Analysis MeSH
- Dentin MeSH
- Humans MeSH
- Elasticity MeSH
- Composite Resins * MeSH
- Materials Testing MeSH
- Dental Materials * MeSH
- Check Tag
- Humans MeSH
- Publication type
- Journal Article MeSH
- Research Support, Non-U.S. Gov't MeSH
- Names of Substances
- Composite Resins * MeSH
- Dental Materials * MeSH
Physically crosslinked low-temperature elastomers were prepared based on linear polydimethylsiloxane (PDMS) elastic chains terminated on both ends with mesogenic building blocks (LC) of azobenzene type. They are generally (and also structurally) highly different from the well-studied LC polymer networks (light-sensitive actuators). The LC units also make up only a small volume fraction in our materials and they do not generate elastic energy upon irradiation, but they act as physical crosslinkers with thermotropic properties. Our elastomers lack permanent chemical crosslinks-their structure is fully linear. The aggregation of the relatively rare, small, and spatially separated terminal LC units nevertheless proved to be a considerably strong crosslinking mechanism. The most attractive product displays a rubber plateau extending over 100 °C, melts near 8 °C, and is soluble in organic solvents. The self-assembly (via LC aggregation) of the copolymer molecules leads to a distinctly lamellar structure indicated by X-ray diffraction (XRD). This structure persists also in melt (polarized light microscopy, XRD), where 1-2 thermotropic transitions occur. The interesting effects of the properties of this lamellar structure on viscoelastic and rheological properties in the rubbery and in the melt state are discussed in a follow-up paper ("Part II"). The copolymers might be of interest as passive smart materials, especially as temperature-controlled elastic/viscoelastic mechanical coupling. Our study focuses on the comparison of physical properties and structure-property relationships in three systems with elastic PDMS segments of different length (8.6, 16.3, and 64.4 repeat units).
- Keywords
- liquid crystals, reversible networks, self-assembly, self-healing, smart materials,
- Publication type
- Journal Article MeSH
Rheological and viscoelastic properties of physically crosslinked low-temperature elastomers were studied. The supramolecularly assembling copolymers consist of linear polydimethylsiloxane (PDMS) elastic chains terminated on both ends with mesogenic building blocks (LC) of azobenzene type. They are generally and also structurally highly different from the well-studied LC polymer networks or LC elastomers: The LC units make up only a small volume fraction in our materials and act as fairly efficient physical crosslinkers with thermotropic properties. The aggregation (nano-phase separation) of the relatively rare, small and spatially separated terminal LC units generates temperature-switched viscoelasticity in the molten copolymers. Their rheological behavior was found to be controlled by an interplay of nano-phase separation of the LC units (growth and splitting of their aggregates) and of the thermotropic transitions in these aggregates (which change their stiffness). As a consequence, multiple gel points (up to three) are observed in temperature scans of the copolymers. The physical crosslinks also can be reversibly disconnected by large mechanical strain in the 'warm' rubbery state, as well as in melt (thixotropy). The kinetics of crosslink formation was found to be fast if induced by temperature and extremely fast in case of internal self-healing after strain damage. Thixotropic loop tests hence display only very small hysteresis in the LC-melt-state, although the melts show very distinct shear thinning. Our study evaluates structure-property relationships in three homologous systems with elastic PDMS segments of different length (8.6, 16.3 and 64.4 repeat units). The studied copolymers might be of interest as passive smart materials, especially as temperature-controlled elastic/viscoelastic mechanical coupling.
- Keywords
- liquid crystals, reversible networks, rheology, self-assembly, self-healing, smart materials,
- Publication type
- Journal Article MeSH
The current study was conducted to evaluate the effect of the addition of selected hydrocolloids [agar (AG), κ-carrageenan (KC), or gelatin (PG); as a total replacement for emulsifying salts] on the viscoelastic properties and microstructure of processed cheese (PC) samples during a storage period of 60 days (at 6 ± 2 °C). In general, PC viscoelastic properties and microstructure were affected by the addition of hydrocolloids and the length of storage time. The evaluated PC reported a more elastic behavior (G′ > G″) over the viscous one. The highest values of viscoelastic moduli (G′; G″; G*) were recorded for PC samples manufactured with KC addition, followed by those prepared with AG and PG. The control sample presented values of viscoelastic moduli similar to those of the PG sample. All PC samples tested had fat globule size values lower than 1 μm. Moreover, PC with AG and KG addition presented similar microstructures and sizes of fat globules.
- Keywords
- hydrocolloids, microstructure, processed cheese, rheology, storage time,
- Publication type
- Journal Article MeSH
Electrorheological (ER) fluids represent smart materials with extensive application potential due to their rheological properties which can be readily changed under an external electric field. In this study, the iron(ii) oxalate particles with rod-like morphology were successfully synthesized by the co-precipitation method using sulphate heptahydrate and oxalic acid dihydrate. The characterization of particles was performed via X-ray diffractometry and scanning electron microscopy. Subsequently, the ER fluids were prepared by dispersing the synthesized particles in silicone oil. The optical microscopy demonstrated the formation of chain-like particle structures upon the application of an electric field. Rheological properties were determined by means of rotational rheometry including creep-recovery experiments. The viscoelastic behavior of systems under investigation in the presence of the electric field was confirmed by the presence of recoverable strain of the system.
- Publication type
- Journal Article MeSH
We synthesized Fe foams using water suspensions of micrometric Fe2O3 powder by reducing and sintering the sublimated Fe oxide green body to Fe under 5% H2/Ar gas. The resultant Fe foam showed aligned lamellar macropores replicating the ice dendrites. The compressive behavior and deformation mechanism of the synthesized Fe foam were studied using an acoustic emission (AE) method, with which we detected sudden localized structural changes in the Fe foam material. The evolution of the deformation mechanism was elucidated using the adaptive sequential k-means (ASK) algorithm; specifically, the plastic deformation of the cell struts was followed by localized cell collapse, which eventually led to fracturing of the cell walls. For potential biomedical applications, the corrosion and biocompatibility characteristics of the two synthesized Fe foams with different porosities (50% vs. 44%) were examined and compared. Despite its larger porosity, the superior corrosion behavior of the Fe foam with 50% porosity can be attributed to its larger pore size and smaller microscopic surface area. Based on the cytotoxicity tests for the extracts of the foams, the Fe foam with 44% porosity showed better cytocompatibility than that with 50% porosity.
- Keywords
- Acoustic emission, Biocompatibility, Cellular material, Deformation mechanisms, Iron (oxide),
- MeSH
- Acoustics * MeSH
- Biocompatible Materials chemistry toxicity MeSH
- Cell Line MeSH
- X-Ray Diffraction MeSH
- Electrochemistry methods MeSH
- Fibroblasts MeSH
- Corrosion MeSH
- Mice MeSH
- Compressive Strength MeSH
- Porosity MeSH
- Materials Testing MeSH
- Viscoelastic Substances chemistry MeSH
- Ferric Compounds chemistry MeSH
- Iron chemistry toxicity MeSH
- Animals MeSH
- Check Tag
- Mice MeSH
- Animals MeSH
- Publication type
- Journal Article MeSH
- Names of Substances
- Biocompatible Materials MeSH
- ferric oxide MeSH Browser
- Viscoelastic Substances MeSH
- Ferric Compounds MeSH
- Iron MeSH
