A concept has been proposed for an installation designed to store excess electricity periodically occurring on the grid. Excess electricity will be used for straw pyrolysis. The main pyrolysis product, gas, will be used to generate electricity using a combustion generator to feed back power into the grid during periods of shortage. The resulting biochar from the pyrolysis can be introduced into the soil to improve soil quality and play a significant role in carbon sequestration. The system uses an electrically heated reactor with a screw conveyor. To preliminarily assess the feasibility of this system, experiments were carried out using wheat straw at temperatures of 300, 400, 500, 600, and 700 °C for the pyrolysis reactor. The resulting gas-to-feedstock mass ratio ranged from 29.04 % at 300 °C to 52.7 % at 700 °C reactor temperature, the biochar mass yield ratio to feedstock varied from 39.41 % to 27.36 % (at 700 °C), and the pyrolysis liquid ranged from 31.55 % to 27.36 % (at 700 °C). The pyrolytic liquid contained a high water content relative to its mass, reaching up to 95.2 % at 700 °C, rendering it less suitable as an energy feedstock. At a reactor temperature of 700 °C, the energy value of the gas produced from the feedstock was twice that of the electricity used for the pyrolysis process. These results suggest the feasibility and operation of the proposed installation.

• Klíčová slova
• Biochar, Carbon sequestration, Electricity storage installation, Energy balance, Pyrolysis products, Straw,
• Publikační typ
• časopisecké články MeSH

Due to the scarcity of wood in some countries, it is necessary to replace it with other raw materials and at the same time use the waste material. The aim of this research is to use poppy waste straw for the efficient conversion of possible lignocellulosic materials - pulps and particleboards. Their suitability for the production of composites is assessed on the basis of selected physical or mechanical properties. Tensile strength index, burst strength index and air permeability by Gurley have been identified as critical properties of pulp made from poppy straw through two delignification methods. The better mechanical properties, i.e., tensile strength index, were achieved at 52.7 N·m/g for the sodium pulp, but the nitrate-alkali method also showed corresponding values at 45.9 N·m/g. Similar parameters to those of bagasse or similar fast-growing plants were achieved in particleboard production. The results of this research are used to evaluate poppy straw as an alternative raw material to produce biocomposites.

• Klíčová slova
• Mechanical properties, Nitrate-alkaline pulp, Particleboard, Poppy straw, Soda pulp,
• Publikační typ
• časopisecké články MeSH

Straw, a natural cellulose-based material, has become part of building elements. Eco-panels, compressed straw in a cardboard casing, is used as building insulation. Eco-panel is a secondary product with excellent insulating properties. If suitably fire-treated (insulation and covering), straw panels' fire resistance may be increased. This contribution deals with monitoring the behavior of eco-panels exposed to a small ignition initiator (flame). The samples consisted of compressed straw boards coated with a 40 mm thick cardboard. Samples were exposed to a flame for 5 and 10 min. The influence of the selected factors (size of the board, orientation of flame with the sample) were compared on the basis of experimentally obtained data: mass loss. The results obtained do not show a statistically significant influence of the position of the sample and the initiating source (flame). The results presented in the article confirm the justifiability of fire tests. As the results of the experiments prove, the position of a small burner for igniting such material is also important. Such weakness of the material can also be eliminated by design solutions in the construction. The experiment on larger samples also confirmed the justifiability of fire tests along with the need for flame retardancy of such material for its safe application in construction.

• Klíčová slova
• eco-panel, fire properties, relative burning rate, small ignition initiator, straw, weight loss,
• Publikační typ
• časopisecké články MeSH

Sustainable development in civil engineering is the clear and necessary goal of the current generation. There are many possibilities for reducing the use of depletable resources. One of them is to use renewable and recyclable materials on a larger scale in the construction industry. One possibility is the application of natural thermal insulators. A typical example is a crushed straw, which is generated as agricultural waste in the Czech Republic. Due to its small dimensions and good thermal insulation parameters, this material can also be used as blown thermal insulation. The research aims to examine the fire resistance of crushed straw as blown insulation. The single-flame source fire test results, thermal attack by a single burning item (SBI) test and large-scale test of a perimeter wall segment are shown. The results show that blown insulation made of crushed straw meets the requirements of fire protection. In addition, crushed straw can be also used to protect load-bearing structures due to its behaviour. This article also shows the production process of crushed straw used as blown insulation in brief.

• Klíčová slova
• blown insulation, civil engineering, crushed straw, fire reaction class, fire test, sustainability,
• Publikační typ
• časopisecké články MeSH

The study aims were focused on profiling eight hydrolytic enzymes by fluorescence method using a multifunctional modular reader and studying the proportion of basic microorganism groups during composting and vermicomposting of sewage sludge mixed with straw pellets in several proportions (0, 25, 50, 75, and 100%). The greatest decrease in enzymatic activity occurred in the first half of composting and vermicomposting. After 4 months of these processes, the least enzymatic activity was observed in the sludge with 50% and also 25% straw addition, indicating that straw is an important means for the rapid production of mature compost from sewage sludge. Enzymatic activity was usually less in the presence of earthworms than in the control treatment because some processes took place in the digestive tract of the earthworm. For the same reason, we observed reduced enzyme activity during fresh feedstock vermicomposting than precomposted material. The final vermicompost from fresh feedstocks exhibited less microbial biomass, and few fungi and G- bacteria compared to precomposted feedstock. The enzymatic activity during composting and vermicomposting of sewage sludge and their mixtures stabilized at the following values: β-D-glucosidase-50 μmol MUFG/h/g dw, acid phosphatase-200 μmol MUFP/h/g dw, arylsulphatase-10 μmol MUFS/h/g dw, lipase-1,000 μmol MUFY/h/g dw, chitinase-50 μmol MUFN/h/g dw, cellobiohydrolase-20 μmol MUFC/h/g dw, alanine aminopeptidase-50 μmol AMCA/h/g dw, and leucine aminopeptidase-50 μmol AMCL/h/g dw. At these and lesser values, these final products can be considered mature and stable.

• Klíčová slova
• composting, earthworms, enzymatic activity, microorganisms, sewage sludge, straw pellets, vermicomposting,
• Publikační typ
• časopisecké články MeSH

Dating of clay bricks (adobe) and plasters is a relevant topic not only for building historians in the Pannonian region. Especially in vernacular architecture in this region, clay with straw amendments is a dominant construction material. The paper presents the potential of the molecular decay of these amendments to establish prediction tools for age based on infrared spectroscopic measurements. Preliminary results revealed spectral differences between the different plant parts, especially culms, nodes, and ear spindles. Based on these results, a first prediction model is presented including 14 historic samples. The coefficient of determination for the validation reached 62.2%, the (RMSE) root mean squared error amounted to 93 years. Taking the limited sample amount and the high material heterogeneity into account, this result can be seen as a promising output. Accordingly, sample size should be increased to a minimum of 100 objects and separate models for the different plant parts should be established.

• Klíčová slova
• FTIR spectroscopy, adobe construction, earth construction, straw amendments, vernacular architecture,
• MeSH
• časové faktory MeSH
• jíl chemie   MeSH
• konstrukční materiály analýza   MeSH
• spektrální analýza MeSH
• stopové prvky analýza   MeSH
• Publikační typ
• časopisecké články MeSH
• Názvy látek
• jíl MeSH
• stopové prvky MeSH

Nonindustrial straw pellets should comply with limitations on the content of ash, chlorine, nitrogen, sulfur, and heavy metals, and have a high melting temperature of ash. To produce such pellets, the properties of straw can be improved by leaching. In known papers, the completion of chlorine washing-out was not controlled. Aims of the paper were to study ash solubility at leaching of straw until completion of chlorine removal and to make a conclusion on studied straw suitability for the production of nonindustrial pellets. Aims were achieved by straw soaking with heating to 100 °C and subsequent plug flow flashing with control of leaching completion by the absence of chlorine in leachate; studying the ash, chlorine, nitrogen, sulfur, and heavy metals content of straw; studying the thermal behavior of ash at heating; determining the initial deformation temperature (IDT) of ash; and comparing the properties of original and leached straw with the specification of straw pellets. Straw leaching until completion of chlorine washing-out provided decreasing chlorine, nitrogen, and sulfur contents below limitations, and the ash content decreased from 7.15 to 3.93% at water leaching to 4.29% at leaching with a 10% solution of acetic acid. In the ternary diagram, the composition of straw ash shifted from a zone of low melting eutectics to zones of high-melting tridymite and cristobalite. The IDT of the original straw ash was 847, 1250 °C after water leaching, and above 1275 °C after leaching with an acetic acid solution. Monitoring the absence of chlorine in the leaching liquid can be applied as a control parameter for straw leaching completion. The original straw was not suitable for the production of nonindustrial pellets because of the high contents of Cl, S, and Cr and the low IDT of ash. All indexes of straw were improved due to leaching, but the Cr content was above limitation. Producers of pellets need to assess straw suitability as to heavy metal content both in the original and leached states.

• Publikační typ
• časopisecké články MeSH

An investigation was carried out using rice straw as a low-cost substrate to study the optimization of xylanase production using a newly identified endospore-forming bacterium, Bacillus altitudinis RS3025. The highest xylanase activity was achieved using 2% rice straw (pretreated with 2% NaOH at 100 °C) at pH 7.0, 37 °C temperature, and with 72-h incubation time. Under the optimized conditions, xylanase activity reached 2518.51 U/mL, which was 11.56-fold higher than the activity under the initial conditions using untreated rice straw as substrate. Enzymatic hydrolysis of the rice straw using crude xylanase of B. altitudinis RS3025 demonstrated the hydrolyzation efficiency of the rice straw waste, especially alkaline rice straw. The highest level of released reducing sugars was 149.78 mg/g substrate. The study demonstrated the successful utilization of rice straw waste for high-level xylanase production using B. altitudinis RS3025 and reducing sugar production using low-cost crude enzyme, which has the advantages of reducing the processing cost and environmental concerns associated with rice straw waste management.

• Klíčová slova
• Bacillus altitudinis, Enzymatic hydrolysis, Enzyme production, Rice straw, Xylanase,
• MeSH
• Bacillus * metabolismus   MeSH
• celulasa * MeSH
• fermentace MeSH
• hydrolýza MeSH
• rýže (rod) * metabolismus   MeSH
• Publikační typ
• časopisecké články MeSH
• Názvy látek
• celulasa * MeSH

The pretreatment methods for enhancing biogas production from oat straw under study include hot maceration, steam explosion, and pressure shockwaves. The micropore area (9, 55, and 64 m(2) g(-1)) inhibitor formations (0, 15, and 0 mL L(-1)) as well as the overall methane yields (67, 179, and 255 CH4 VS t(-1)) were robustly analyzed. It was confirmed that the operating conditions of the steam explosion must be precisely tailored to the substrate. Furthermore, it was beneficial to prepend the hot maceration before the steam explosion and the pressure shockwaves. The second alternative may give increased methane yields (246 in comparison to 273 CH4 VS t(-1)); however, the application of pressure shockwaves still faces limitations for deployment on a commercial scale.

• MeSH
• anaerobióza MeSH
• biochemické jevy MeSH
• biopaliva * MeSH
• exploze MeSH
• fermentace MeSH
• methan analýza   MeSH
• odpadky - odstraňování metody   MeSH
• oves MeSH
• pára MeSH
• rázové vlny s vysokou energií MeSH
• Publikační typ
• časopisecké články MeSH
• práce podpořená grantem MeSH
• Názvy látek
• biopaliva * MeSH
• methan MeSH
• pára MeSH

Five white-rot basidiomycetes were evaluated for their potential to improve ruminal degradation of wheat straw. Polyorus brumalis, Lyophyllum ulmarium III, Trametes gibbosa, Pleurotus ostreatus, and a Pleurotus ostreatus mutant were incubated on wheat straw for 30 d at 28 degrees C. Detergent fiber, crude protein and in vitro dry matter digestibility (IVDMD) were determined. The results showed increasing crude protein and ash contents in fungus-treated straw. IVDMD values were increased in straws treated with P. ostreatus, P. ostreatus mutant and T. gibbosa only. Relative to untreated wheat straw the detergent fiber content-neutral detergent fiber (NDF), and acid detergent fiber (ADF) was reduced in fungus-treated straw and out of three fractions-hemicellulose, cellulose, and lignin, hemicellulose showed the largest proportionate loss whereas lignin the smallest one in all 5 samples of fungus treated straw.

• MeSH
• Basidiomycota metabolismus   MeSH
• celulosa analýza   metabolismus   MeSH
• krmivo pro zvířata mikrobiologie   MeSH
• lignin analýza   metabolismus   MeSH
• polysacharidy analýza   metabolismus   MeSH
• potravní vláknina analýza   MeSH
• proteiny analýza   MeSH
• pšenice metabolismus   mikrobiologie   MeSH
• Publikační typ
• časopisecké články MeSH
• práce podpořená grantem MeSH
• Research Support, U.S. Gov't, Non-P.H.S. MeSH
• Názvy látek
• celulosa MeSH
• hemicellulose MeSH Prohlížeč
• lignin MeSH
• polysacharidy MeSH
• potravní vláknina MeSH
• proteiny MeSH