Sorption
Dotaz
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Sorption properties of selected sorbents suitable to remove Platinum group cytostatics from hospital waste water and from model solutions of selected Pt group cytostatics were evaluated. Suitable sorbents Clinoptilolite, Bentonite (from Braňany, Czech Republic), Lufa and Supersorbon were selected for testing the Platinum cytostatics removal by the process of sorption from contaminated waste water. Supersorbon activated coal and Bentonite (Braňany) were evaluated as efficient sorbents suitable for all tested Pt cytostatics, which probably relates to their structure the largest volume of pores, porosity and specific surface area. During testing it was found that Platinum compounds precipitate out of the solutions, while this was insignificant only in the Carboplatin solution. This reached up to 85 % in several tests with Cisplatin and Oxali-platin solutions. It was shown that this phenomena occur even in case of the real hospital waste water.
- Klíčová slova
- cytostatika platinové řady, metody čištění kontaminovaných vod, sorpční experimenty, sorpce, sorbenty,
- MeSH
- cytostatické látky toxicita MeSH
- nemocnice MeSH
- odpadní voda * analýza toxicita MeSH
- platina toxicita MeSH
- sloučeniny platiny toxicita MeSH
- Publikační typ
- práce podpořená grantem MeSH
The sorption of 3 pharmaceuticals, which may exist in 4 different forms depending on the solution pH (irbesartan in cationic, neutral and anionic, fexofenadine in cationic, zwitter-ionic and anionic, and citalopram cationic and neutral), in seven different soils was studied. The measured sorption isotherms were described by Freundlich equations, and the sorption coefficients, KF (for the fixed n exponent for each compound), were related to the soil properties to derive relationships for estimating the sorption coefficients from the soil properties (i.e., pedotransfer rules). The largest sorption was obtained for citalopram (average KF value for n = 1 was 1838 cm3 g-1) followed by fexofenadine (KF = 35.1 cm3/n μg1-1/n g-1, n = 1.19) and irbesartan (KF = 3.96 cm3/n μg1-1/n g-1, n = 1.10). The behavior of citalopram (CIT) in soils was different than the behaviors of irbesartan (IRB) and fexofenadine (FEX). Different trends were documented according to the correlation coefficients between the KF values for different compounds (RIRB,FEX = 0.895, p-value<0.01; RIRB,CIT = -0.835, p-value<0.05; RFEX,CIT = -0.759, p-value<0.05) and by the reverse relationships between the KF values and soil properties in the pedotransfer functions. While the KF value for citalopram was positively related to base cation saturation (BCS) or sorption complex saturation (SCS) and negatively correlated to the organic carbon content (Cox), the KF values of irbesartan and fexofenadine were negatively related to BCS, SCS or the clay content and positively related to Cox. The best estimates were obtained by combining BCS and Cox for citalopram (R2 = 93.4), SCS and Cox for irbesartan (R2 = 96.3), and clay content and Cox for fexofenadine (R2 = 82.9).
- MeSH
- adsorpce fyziologie MeSH
- bifenylové sloučeniny analýza metabolismus MeSH
- citalopram analýza metabolismus MeSH
- látky znečišťující půdu analýza metabolismus MeSH
- odpadní voda analýza chemie MeSH
- půda chemie MeSH
- silikáty hliníku chemie MeSH
- terfenadin analogy a deriváty analýza metabolismus MeSH
- tetrazoly analýza metabolismus MeSH
- zemědělství MeSH
- Publikační typ
- časopisecké články MeSH
The aim of the present study was to investigate tebuconazole sorption on common soil minerals (birnessite, ferrihydrite, goethite, calcite and illite) and humic acids (representing soil organic matter). Tebuconazole was used (i) in the commercial form Horizon 250 EW and (ii) as an analytical grade pure chemical. In the experiment with the commercially available tebuconazole, a significant pH-dependent sorption onto the oxides was observed (decreasing sorption with increasing pH). The highest sorption was found for ferrihydrite due to its high specific surface area, followed by humic acids, birnessite, goethite and illite. No detectable sorption was found for calcite. The sorption of analytical grade tebuconazole on all selected minerals was significantly lower compared to the commercial product. The sorption was the highest for humic acids, followed by ferrihydrite and illite and almost negligible for goethite and birnessite without any pH dependence. Again, no sorption was observed for calcite. The differences in sorption of the commercially available and analytical grade tebuconazole can be attributed to the additives (e.g., solvents) present in the commercial product. This work proved the importance of soil mineralogy and composition of the commercially available pesticides on the behavior of tebuconazole in soils.
From the physical point of view, soil is a heterogenic polydisperse system. It often becomes a place of a secondary contamination during extinguishing uncontrolled areal fires in nature. Foam extinguishing agents (FEAs), used at these events, basically contain surface active substances and perfluorinated compounds. These tend to be captured in the soil matrix due to their specific properties. Contaminants could be partly flushed out with rainwater, which causes several times dilution of contamination and lower ecotoxic activity. However in the dry season, foam solution infiltrates into the bed soil without any dilution. This study deals with the direct influence of soil the sorption complex on ecotoxicity of five selected FEAs, i.e. Expyrol F 15, Finiflam F 15, Moussol APS F 15, Pyrocool B and Sthamex F 15. The substances tested were prepared in concentration of work solution and then applied on standard soil matrix LUFA 2.3. For experimental purposes, a column infiltration apparatus was designed and compiled. Filtrates were collected and then tested using the plant organisms Sinapis alba and Allium cepa L. The study compared ecotoxicologic effects of filtrates with an original work solution. Moussol APS F 15 seems to be the least ecotoxic of the FEAs tested. A direct influence of soil sorption complex onto ecotoxicity reduction was also established. This finding demonstrates the sorption ability of soil particles and ion exchange activity of the soil matrix. It is a positive finding for biota of aquatic environment, yet at the expense of those in soil.
